Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U)

The reaction of (C Me ) AnCl (An = Th, U) with 2.8 or 4 equivalents of LiNMe , respectively, affords (C Me ) An(NMe ) in high yields. In addition to improved syntheses, the solid-state structures, voltammetric data, and UV-visible-NIR spectra for these classic actinide bis(dimethylamido) complexes a...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2017-08, Vol.46 (34), p.11208-11213
Main Authors: Erickson, K A, Kagan, B D, Scott, B L, Morris, D E, Kiplinger, J L
Format: Article
Language:English
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INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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cited_by cdi_FETCH-LOGICAL-c1262-fef8d6d15d235b1a8f7949d3bc28af2b22378fb9972b03948ea85931de0bb2c83
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container_issue 34
container_start_page 11208
container_title Dalton transactions : an international journal of inorganic chemistry
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creator Erickson, K A
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description The reaction of (C Me ) AnCl (An = Th, U) with 2.8 or 4 equivalents of LiNMe , respectively, affords (C Me ) An(NMe ) in high yields. In addition to improved syntheses, the solid-state structures, voltammetric data, and UV-visible-NIR spectra for these classic actinide bis(dimethylamido) complexes are presented for the first time.
doi_str_mv 10.1039/c7dt02373a
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title Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U)
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