Grain Growth in Nanocrystalline Mg-Al Thin Films

• Published in: Metallurgical and materials transactions. A, Physical metallurgy and materials science Physical metallurgy and materials science, 2017-12, Vol.48 (12), p.6118-6125
• Main Authors: Kruska, Karen, Rohatgi, Aashish, Vemuri, Rama S., Kovarik, Libor, Moser, Trevor H., Evans, James E., Browning, Nigel D.
• Format: Article
• Language: English
• Subjects: Activation energy; Aluminum base alloys; Characterization and Evaluation of Materials; Chemistry and Materials Science; Electron microscopy; Grain boundaries; Grain growth; Grooves; Heat treatment; Magnesium base alloys; Magnetron sputtering; MATERIALS SCIENCE; Metallic Materials; Metallurgy; Microstructure; Nanotechnology; Precipitates; Structural Materials; Supersaturation; Surface diffusion; Surfaces and Interfaces; Thin Films
• ISSN: 1073-5623; 1543-1940
• DOI: 10.1007/s11661-017-4350-0

An improved understanding of grain growth kinetics in nanocrystalline materials, and in metals and alloys in general, is of continuing interest to the scientific community. In this study, Mg-Al thin films containing ~10 wt pct Al and with 14.5 nm average grain size were produced by magnetron sputtering and subjected to heat treatments. The grain growth evolution in the early stages of heat treatment at 423 K, 473 K, and 573 K (150 °C, 200 °C, and 300 °C) was observed with transmission electron microscopy and analyzed based upon the classical equation developed by Burke and Turnbull. The grain growth exponent was found to be 7 ± 2 and the activation energy for grain growth was 31.1 ± 13.4 kJ/mol, the latter being significantly lower than in bulk Mg-Al alloys. The observed grain growth kinetics are explained by the Al supersaturation in the matrix and the pinning effects of the rapidly forming beta precipitates and possibly shallow grain boundary grooves. The low activation energy is attributed to the rapid surface diffusion which is dominant in thin film systems.