High‐Performance Semitransparent Ternary Organic Solar Cells

Semitransparent organic solar cells (STOSCs) are ideal candidates for building‐integrated photovoltaics. Power conversion efficiency (PCE) is one of the most important parameters of STOSCs, which is typically limited by the intrinsic narrow absorption of thin active layer. Ternary structure is demon...

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Bibliographic Details
Published in:Advanced functional materials 2018-12, Vol.28 (49), p.n/a
Main Authors: Xie, Yuanpeng, Huo, Lijun, Fan, Bingbing, Fu, Huiting, Cai, Yunhao, Zhang, Lin, Li, Zhiyi, Wang, Ying, Ma, Wei, Chen, Yiwang, Sun, Yanming
Format: Article
Language:English
Subjects:
average visible transmittance
Color vision
efficiency
Electromagnetic absorption
Energy conversion efficiency
Materials science
Morphology
Organic chemistry
organic solar cells
Photovoltaic cells
semitransparent devices
Solar cells
ternary blends
Ternary systems
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Summary:Semitransparent organic solar cells (STOSCs) are ideal candidates for building‐integrated photovoltaics. Power conversion efficiency (PCE) is one of the most important parameters of STOSCs, which is typically limited by the intrinsic narrow absorption of thin active layer. Ternary structure is demonstrated as an efficient approach to broaden the light absorption and manipulate the morphology, thus leading to improved PCEs by introducing a third component into the binary system. However, STOSCs based on ternary systems are rarely studied. In this contribution, semitransparent ternary solar cells are fabricated using a wide‐bandgap (E g = 2.10 eV) polymer donor, PBT1‐S, as the third component. It is found that the addition of a small amount of PBT1‐S to PTB7‐Th:PC71BM blend has a negligible influence on its average visible transmittance (AVT) and color perception. A PCE of 9.2% is achieved for the champion ternary device with 20% AVT, which is one of the highest values for STOSCs. The results indicate that ternary structure is a promising approach for the fabrication of high‐performance STOSCs. Semitransparent organic solar cells (STOSCs) based on ternary structure are rarely studied. Here, a high efficiency of 9.2% is achieved for the champion semitransparent ternary device with 20% average visible transmittance, which is among the highest power conversion efficiencies reported for STOSCs so far. This indicates that the ternary structure is a promising strategy to fabricate high‐performance STOSCs.
ISSN:1616-301X
1616-3028
DOI:10.1002/adfm.201800627