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Functionalized TiO2 Nanoparticles for Use for in Situ Anion Immobilization
Anatase particles (40−60 nm) were coated with an organosilane monolayer terminated with an ethylenediamine (EDA) ligand. These functionalized nanoparticles (FNPs) were then treated with an aqueous solution of Cu(II) to create a cationic Cu−EDA complex bound to the nanoparticle surface. Cu(II) and ED...
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| Published in: | Environmental science & technology 2005-09, Vol.39 (18), p.7306-7310 |
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| container_end_page | 7310 |
| container_issue | 18 |
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| container_title | Environmental science & technology |
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| creator | Mattigod, Shas V Fryxell, Glen E Alford, Kentin Gilmore, Tyler Parker, Kent Serne, Jeff Engelhard, Mark |
| description | Anatase particles (40−60 nm) were coated with an organosilane monolayer terminated with an ethylenediamine (EDA) ligand. These functionalized nanoparticles (FNPs) were then treated with an aqueous solution of Cu(II) to create a cationic Cu−EDA complex bound to the nanoparticle surface. Cu(II) and EDA ligand incorporation were confirmed by X-ray photoelectron spectroscopy (XPS) analysis. The Cu(EDA)2 FNP was then studied for its binding affinity for pertechnetate anion from a Hanford groundwater matrix. The Cu(EDA)2 FNP was also evaluated for its injectability into a porous medium for possible application as a subsurface semipermeable reactive barrier. Injection was readily accomplished, and resulted in a highly uniform distribution of the FNP sorbent in the test column. |
| doi_str_mv | 10.1021/es048982l |
| format | article |
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These functionalized nanoparticles (FNPs) were then treated with an aqueous solution of Cu(II) to create a cationic Cu−EDA complex bound to the nanoparticle surface. Cu(II) and EDA ligand incorporation were confirmed by X-ray photoelectron spectroscopy (XPS) analysis. The Cu(EDA)2 FNP was then studied for its binding affinity for pertechnetate anion from a Hanford groundwater matrix. The Cu(EDA)2 FNP was also evaluated for its injectability into a porous medium for possible application as a subsurface semipermeable reactive barrier. Injection was readily accomplished, and resulted in a highly uniform distribution of the FNP sorbent in the test column.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es048982l</identifier><identifier>PMID: 16201663</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Adsorption ; ANIONS ; Applied sciences ; Aqueous solutions ; Cations ; CHELATING AGENTS ; Copper - analysis ; Cross-disciplinary physics: materials science; rheology ; Earth sciences ; Earth, ocean, space ; Electrochemistry ; Engineering and environment geology. Geothermics ; Environmental Molecular Sciences Laboratory ; ENVIRONMENTAL SCIENCES ; Ethylenediamines - analysis ; Exact sciences and technology ; GROUND WATER ; Groundwaters ; HANFORD RESERVATION ; Ions ; Kinetics ; Ligands ; Magnetic Resonance Spectroscopy ; Materials science ; Models, Chemical ; Nanoparticles ; Nanoscale materials and structures: fabrication and characterization ; NANOSTRUCTURES ; Nanostructures - analysis ; Nanotechnology ; Natural water pollution ; NUCLEAR FUEL CYCLE AND FUEL MATERIALS ; Organic-inorganic hybrid nanostructures ; Permeability ; PERTECHNETATES ; Physics ; Pollution ; Pollution, environment geology ; Powders ; REMEDIAL ACTION ; Sodium Pertechnetate Tc 99m - analysis ; Spectrometry, X-Ray Emission - methods ; Spectroscopy, Fourier Transform Infrared ; SURFACE PROPERTIES ; Technetium - chemistry ; Titanium - analysis ; TITANIUM OXIDES ; Water Pollutants ; Water Purification - methods ; Water treatment ; Water treatment and pollution</subject><ispartof>Environmental science & technology, 2005-09, Vol.39 (18), p.7306-7310</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2005 INIST-CNRS</rights><rights>Copyright American Chemical Society Sep 15, 2005</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17118632$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16201663$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/15020415$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Mattigod, Shas V</creatorcontrib><creatorcontrib>Fryxell, Glen E</creatorcontrib><creatorcontrib>Alford, Kentin</creatorcontrib><creatorcontrib>Gilmore, Tyler</creatorcontrib><creatorcontrib>Parker, Kent</creatorcontrib><creatorcontrib>Serne, Jeff</creatorcontrib><creatorcontrib>Engelhard, Mark</creatorcontrib><creatorcontrib>Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)</creatorcontrib><title>Functionalized TiO2 Nanoparticles for Use for in Situ Anion Immobilization</title><title>Environmental science & technology</title><addtitle>Environ. Sci. Technol</addtitle><description>Anatase particles (40−60 nm) were coated with an organosilane monolayer terminated with an ethylenediamine (EDA) ligand. These functionalized nanoparticles (FNPs) were then treated with an aqueous solution of Cu(II) to create a cationic Cu−EDA complex bound to the nanoparticle surface. Cu(II) and EDA ligand incorporation were confirmed by X-ray photoelectron spectroscopy (XPS) analysis. The Cu(EDA)2 FNP was then studied for its binding affinity for pertechnetate anion from a Hanford groundwater matrix. The Cu(EDA)2 FNP was also evaluated for its injectability into a porous medium for possible application as a subsurface semipermeable reactive barrier. Injection was readily accomplished, and resulted in a highly uniform distribution of the FNP sorbent in the test column.</description><subject>Adsorption</subject><subject>ANIONS</subject><subject>Applied sciences</subject><subject>Aqueous solutions</subject><subject>Cations</subject><subject>CHELATING AGENTS</subject><subject>Copper - analysis</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Electrochemistry</subject><subject>Engineering and environment geology. Geothermics</subject><subject>Environmental Molecular Sciences Laboratory</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>Ethylenediamines - analysis</subject><subject>Exact sciences and technology</subject><subject>GROUND WATER</subject><subject>Groundwaters</subject><subject>HANFORD RESERVATION</subject><subject>Ions</subject><subject>Kinetics</subject><subject>Ligands</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Materials science</subject><subject>Models, Chemical</subject><subject>Nanoparticles</subject><subject>Nanoscale materials and structures: fabrication and characterization</subject><subject>NANOSTRUCTURES</subject><subject>Nanostructures - analysis</subject><subject>Nanotechnology</subject><subject>Natural water pollution</subject><subject>NUCLEAR FUEL CYCLE AND FUEL MATERIALS</subject><subject>Organic-inorganic hybrid nanostructures</subject><subject>Permeability</subject><subject>PERTECHNETATES</subject><subject>Physics</subject><subject>Pollution</subject><subject>Pollution, environment geology</subject><subject>Powders</subject><subject>REMEDIAL ACTION</subject><subject>Sodium Pertechnetate Tc 99m - analysis</subject><subject>Spectrometry, X-Ray Emission - methods</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>SURFACE PROPERTIES</subject><subject>Technetium - chemistry</subject><subject>Titanium - analysis</subject><subject>TITANIUM OXIDES</subject><subject>Water Pollutants</subject><subject>Water Purification - methods</subject><subject>Water treatment</subject><subject>Water treatment and pollution</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNpF0U1v2zAMBmBh6LCm3Q79A4XRokdvpL4sH4OgX1mwDEiK9SbIiowqdezUkoFtv35qkzUnHvjwhUQScobwFYHiNxeAq1LR5gMZoaCQCyXwiIwAkOUlk4_H5CSENQBQBuoTOUZJAaVkIzK9GVobfdeaxv91q2zp5zT7Ydpua_robeNCVnd99hDcW_VttvBxyMZtGsnuN5uu8mnQvCZ8Jh9r0wT3ZV9PycPN9XJyl8_mt_eT8Sw3TNKYi4oXJRZolROOl7gCS5lF51JbKigLVXOwvKoMB2bKgoqC8lqBFVXNK5TslFzucrsQvQ7WR2efbNe2zkaNAihwFEld7NS2714GF6Jed0Ofvhl0WgJKXgpM6HyPhmrjVnrb-43p_-j_-0ngag9MsKape9NaHw6uQFSS0eTynfMhut_vfdM_a1mwQujlz4Xm8vvk1-3yUU8PucaGw8MQ9Os99fs92T_R2Ive</recordid><startdate>20050915</startdate><enddate>20050915</enddate><creator>Mattigod, Shas V</creator><creator>Fryxell, Glen E</creator><creator>Alford, Kentin</creator><creator>Gilmore, Tyler</creator><creator>Parker, Kent</creator><creator>Serne, Jeff</creator><creator>Engelhard, Mark</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>SOI</scope><scope>OTOTI</scope></search><sort><creationdate>20050915</creationdate><title>Functionalized TiO2 Nanoparticles for Use for in Situ Anion Immobilization</title><author>Mattigod, Shas V ; Fryxell, Glen E ; Alford, Kentin ; Gilmore, Tyler ; Parker, Kent ; Serne, Jeff ; Engelhard, Mark</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a362t-5b479171c8e5e491d0c23c1eea36680978f40c4bba403a9725724f80c5bf4b163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Adsorption</topic><topic>ANIONS</topic><topic>Applied sciences</topic><topic>Aqueous solutions</topic><topic>Cations</topic><topic>CHELATING AGENTS</topic><topic>Copper - analysis</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Earth sciences</topic><topic>Earth, ocean, space</topic><topic>Electrochemistry</topic><topic>Engineering and environment geology. Geothermics</topic><topic>Environmental Molecular Sciences Laboratory</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>Ethylenediamines - analysis</topic><topic>Exact sciences and technology</topic><topic>GROUND WATER</topic><topic>Groundwaters</topic><topic>HANFORD RESERVATION</topic><topic>Ions</topic><topic>Kinetics</topic><topic>Ligands</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Materials science</topic><topic>Models, Chemical</topic><topic>Nanoparticles</topic><topic>Nanoscale materials and structures: fabrication and characterization</topic><topic>NANOSTRUCTURES</topic><topic>Nanostructures - analysis</topic><topic>Nanotechnology</topic><topic>Natural water pollution</topic><topic>NUCLEAR FUEL CYCLE AND FUEL MATERIALS</topic><topic>Organic-inorganic hybrid nanostructures</topic><topic>Permeability</topic><topic>PERTECHNETATES</topic><topic>Physics</topic><topic>Pollution</topic><topic>Pollution, environment geology</topic><topic>Powders</topic><topic>REMEDIAL ACTION</topic><topic>Sodium Pertechnetate Tc 99m - analysis</topic><topic>Spectrometry, X-Ray Emission - methods</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>SURFACE PROPERTIES</topic><topic>Technetium - chemistry</topic><topic>Titanium - analysis</topic><topic>TITANIUM OXIDES</topic><topic>Water Pollutants</topic><topic>Water Purification - methods</topic><topic>Water treatment</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mattigod, Shas V</creatorcontrib><creatorcontrib>Fryxell, Glen E</creatorcontrib><creatorcontrib>Alford, Kentin</creatorcontrib><creatorcontrib>Gilmore, Tyler</creatorcontrib><creatorcontrib>Parker, Kent</creatorcontrib><creatorcontrib>Serne, Jeff</creatorcontrib><creatorcontrib>Engelhard, Mark</creatorcontrib><creatorcontrib>Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><collection>OSTI.GOV</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mattigod, Shas V</au><au>Fryxell, Glen E</au><au>Alford, Kentin</au><au>Gilmore, Tyler</au><au>Parker, Kent</au><au>Serne, Jeff</au><au>Engelhard, Mark</au><aucorp>Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Functionalized TiO2 Nanoparticles for Use for in Situ Anion Immobilization</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>2005-09-15</date><risdate>2005</risdate><volume>39</volume><issue>18</issue><spage>7306</spage><epage>7310</epage><pages>7306-7310</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>Anatase particles (40−60 nm) were coated with an organosilane monolayer terminated with an ethylenediamine (EDA) ligand. These functionalized nanoparticles (FNPs) were then treated with an aqueous solution of Cu(II) to create a cationic Cu−EDA complex bound to the nanoparticle surface. Cu(II) and EDA ligand incorporation were confirmed by X-ray photoelectron spectroscopy (XPS) analysis. The Cu(EDA)2 FNP was then studied for its binding affinity for pertechnetate anion from a Hanford groundwater matrix. The Cu(EDA)2 FNP was also evaluated for its injectability into a porous medium for possible application as a subsurface semipermeable reactive barrier. Injection was readily accomplished, and resulted in a highly uniform distribution of the FNP sorbent in the test column.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>16201663</pmid><doi>10.1021/es048982l</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-936X |
| ispartof | Environmental science & technology, 2005-09, Vol.39 (18), p.7306-7310 |
| issn | 0013-936X 1520-5851 |
| language | eng |
| recordid | cdi_osti_scitechconnect_15020415 |
| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| subjects | Adsorption ANIONS Applied sciences Aqueous solutions Cations CHELATING AGENTS Copper - analysis Cross-disciplinary physics: materials science rheology Earth sciences Earth, ocean, space Electrochemistry Engineering and environment geology. Geothermics Environmental Molecular Sciences Laboratory ENVIRONMENTAL SCIENCES Ethylenediamines - analysis Exact sciences and technology GROUND WATER Groundwaters HANFORD RESERVATION Ions Kinetics Ligands Magnetic Resonance Spectroscopy Materials science Models, Chemical Nanoparticles Nanoscale materials and structures: fabrication and characterization NANOSTRUCTURES Nanostructures - analysis Nanotechnology Natural water pollution NUCLEAR FUEL CYCLE AND FUEL MATERIALS Organic-inorganic hybrid nanostructures Permeability PERTECHNETATES Physics Pollution Pollution, environment geology Powders REMEDIAL ACTION Sodium Pertechnetate Tc 99m - analysis Spectrometry, X-Ray Emission - methods Spectroscopy, Fourier Transform Infrared SURFACE PROPERTIES Technetium - chemistry Titanium - analysis TITANIUM OXIDES Water Pollutants Water Purification - methods Water treatment Water treatment and pollution |
| title | Functionalized TiO2 Nanoparticles for Use for in Situ Anion Immobilization |
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