An experimentally calibrated thermobarometric solubility model for titanium in coesite (TitaniC)

• Published in: Contributions to mineralogy and petrology 2019-04, Vol.174 (4), p.1-13, Article 34
• Main Authors: Osborne, Zach R., Thomas, Jay B., Nachlas, William O., Baldwin, Suzanne L., Holycross, Megan E., Spear, Frank S., Watson, E. Bruce
• Format: Article
• Language: English
• Subjects: Analytical methods; Anatase; Calibration; Cathodoluminescence; Coesite; Computational fluid dynamics; Crystallization; Crystals; Cylinders; Diamonds; Earth and Environmental Science; Earth Sciences; Electron probes; Fluids; Gasoline; Geology; Graphite; Least squares method; Mineral Resources; Mineralogy; Original Paper; Petrology; Phase equilibria; Powders (Particulate matter); Pressure effects; Raman spectroscopy; Rutile; Silica; Silicon dioxide; Silver; Solubility; Spectroscopy; Stability; Temperature; Titanium; Titanium dioxide; X ray absorption; Zircon; Zirconium; Zirconium dioxide; Zirconium oxide
• ISSN: 0010-7999; 1432-0967
• DOI: 10.1007/s00410-019-1575-5

Experiments were conducted to quantify the temperature and pressure effects on the solubility of titanium in coesite. Powdered amorphous silica, titania (anatase), zirconia, and water were added to silver capsules and run in the coesite stability field (at 32, 35, and 40 kbar) from 700 to 1050 °C using a piston–cylinder apparatus. Crystallization of coesite, rutile, and zircon from silica-, titania-, and zircon-saturated aqueous fluids was confirmed by Raman spectroscopy. Cathodoluminescence images and electron microprobe measurements showed that coesite crystals are relatively homogenous. The Ti concentrations of coesite crystals are significantly higher than concentrations predicted using the Ti-in-quartz calibration (Wark and Watson in Contrib Mineral Petrol 152:743–754, 2006 . https://doi.org/10.1007/s00410-006-0132-1 ; Thomas et al. in Contrib Mineral Petrol 160:743–759, 2010 . https://doi.org/10.1007/s00410-010-0505-3 ). Titanium K-edge X-ray absorption near edge structure (XANES) measurements demonstrate that Ti 4+ substitutes for Si 4+ on fourfold tetrahedral sites in coesite at all conditions studied. A model was calibrated to describe the effects of pressure and temperature on the solubility of titanium in coesite by using a least-squares method to fit Ti concentrations in coesite to the simple expression: R T ln X TiO 2 coesite = - 55.068 + 0.00195 × T ( K ) - 1.234 × P ( kbar ) + R T ln a TiO 2 rutile , where R is the gas constant 8.3145 × 10 −3  kJ/K, P is pressure in kbar, T is temperature in kelvin, X TiO 2 coesite is the mole fraction of TiO 2 in coesite, and a TiO 2 rutile is the activity of TiO 2 in the system referenced to rutile. Ti-in-coesite solubility can be used as a thermobarometer for natural samples when used in combination with another indicator of temperature or pressure, such as another thermobarometer in a cogenetic mineral (e.g. rutile) or other phase equilibria (e.g. graphite = diamond). Applications of the Ti-in-coesite thermobarometer to samples from the western Alps and Papua New Guinea are presented.