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Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion
Reactions of inorganic macrocyclic polytungstate cavitands K 28 Li 5 H 7 [P 8 W 48 O 184 ]·92H 2 O or Li 17 (NH 4 ) 21 H 2 [P 8 W 48 O 184 ]·85H 2 O with (NH 4 )[NbO(C 2 O 4 ) 2 (H 2 O) 2 ]·3H 2 O (Nb–Ox) in aqueous solution lead to incorporation of up to five {NbO(H 2 O)} 3+ units into the {P 8 W 4...
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| Published in: | New journal of chemistry 2019-06, Vol.43 (25), p.9943-9952 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c1314-f9daaa8c862be2366959f05c10d45ff18ff7ca663709a1e2c22c3c7e47a66203 |
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| cites | cdi_FETCH-LOGICAL-c1314-f9daaa8c862be2366959f05c10d45ff18ff7ca663709a1e2c22c3c7e47a66203 |
| container_end_page | 9952 |
| container_issue | 25 |
| container_start_page | 9943 |
| container_title | New journal of chemistry |
| container_volume | 43 |
| creator | Shmakova, Alexandra A. Volchek, Victoria V. Yanshole, Vadim Kompankov, Nikolay B. Martin, Nicolas P. Nyman, May Abramov, Pavel A. Sokolov, Maxim N. |
| description | Reactions of inorganic macrocyclic polytungstate cavitands K
28
Li
5
H
7
[P
8
W
48
O
184
]·92H
2
O or Li
17
(NH
4
)
21
H
2
[P
8
W
48
O
184
]·85H
2
O with (NH
4
)[NbO(C
2
O
4
)
2
(H
2
O)
2
]·3H
2
O (Nb–Ox) in aqueous solution lead to incorporation of up to five {NbO(H
2
O)}
3+
units into the {P
8
W
48
} cavity. The most stable species contain four {NbO(H
2
O)}
3+
units. The uptake of {NbO(H
2
O)}
3+
was determined by corroborative methods including single crystal XRD, inductively coupled plasma atomic emission spectroscopy (ICP-AES),
31
P and
13
C nuclear magnetic resonance (NMR), C–H–N elemental analysis (EA) and thermal gravimetric analysis (TGA). Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and small angle X-ray scattering (SAXS). |
| doi_str_mv | 10.1039/C9NJ01907C |
| format | article |
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28
Li
5
H
7
[P
8
W
48
O
184
]·92H
2
O or Li
17
(NH
4
)
21
H
2
[P
8
W
48
O
184
]·85H
2
O with (NH
4
)[NbO(C
2
O
4
)
2
(H
2
O)
2
]·3H
2
O (Nb–Ox) in aqueous solution lead to incorporation of up to five {NbO(H
2
O)}
3+
units into the {P
8
W
48
} cavity. The most stable species contain four {NbO(H
2
O)}
3+
units. The uptake of {NbO(H
2
O)}
3+
was determined by corroborative methods including single crystal XRD, inductively coupled plasma atomic emission spectroscopy (ICP-AES),
31
P and
13
C nuclear magnetic resonance (NMR), C–H–N elemental analysis (EA) and thermal gravimetric analysis (TGA). Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and small angle X-ray scattering (SAXS).</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/C9NJ01907C</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aqueous solutions ; Atomic beam spectroscopy ; Chemical analysis ; Crystallography ; Emission analysis ; Gravimetric analysis ; Inductively coupled plasma ; Niobium oxides ; NMR ; Nuclear magnetic resonance ; Polyelectrolytes ; Single crystals ; Small angle X ray scattering ; Speciation ; Thermal analysis</subject><ispartof>New journal of chemistry, 2019-06, Vol.43 (25), p.9943-9952</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1314-f9daaa8c862be2366959f05c10d45ff18ff7ca663709a1e2c22c3c7e47a66203</citedby><cites>FETCH-LOGICAL-c1314-f9daaa8c862be2366959f05c10d45ff18ff7ca663709a1e2c22c3c7e47a66203</cites><orcidid>0000-0002-1787-0518 ; 0000-0003-4479-5100 ; 0000-0003-1693-2323 ; 0000-0003-1512-3049 ; 0000-0001-9361-4594 ; 0000000344795100 ; 0000000193614594 ; 0000000316932323 ; 0000000315123049 ; 0000000217870518</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/1525505$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Shmakova, Alexandra A.</creatorcontrib><creatorcontrib>Volchek, Victoria V.</creatorcontrib><creatorcontrib>Yanshole, Vadim</creatorcontrib><creatorcontrib>Kompankov, Nikolay B.</creatorcontrib><creatorcontrib>Martin, Nicolas P.</creatorcontrib><creatorcontrib>Nyman, May</creatorcontrib><creatorcontrib>Abramov, Pavel A.</creatorcontrib><creatorcontrib>Sokolov, Maxim N.</creatorcontrib><title>Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion</title><title>New journal of chemistry</title><description>Reactions of inorganic macrocyclic polytungstate cavitands K
28
Li
5
H
7
[P
8
W
48
O
184
]·92H
2
O or Li
17
(NH
4
)
21
H
2
[P
8
W
48
O
184
]·85H
2
O with (NH
4
)[NbO(C
2
O
4
)
2
(H
2
O)
2
]·3H
2
O (Nb–Ox) in aqueous solution lead to incorporation of up to five {NbO(H
2
O)}
3+
units into the {P
8
W
48
} cavity. The most stable species contain four {NbO(H
2
O)}
3+
units. The uptake of {NbO(H
2
O)}
3+
was determined by corroborative methods including single crystal XRD, inductively coupled plasma atomic emission spectroscopy (ICP-AES),
31
P and
13
C nuclear magnetic resonance (NMR), C–H–N elemental analysis (EA) and thermal gravimetric analysis (TGA). Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and small angle X-ray scattering (SAXS).</description><subject>Aqueous solutions</subject><subject>Atomic beam spectroscopy</subject><subject>Chemical analysis</subject><subject>Crystallography</subject><subject>Emission analysis</subject><subject>Gravimetric analysis</subject><subject>Inductively coupled plasma</subject><subject>Niobium oxides</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Polyelectrolytes</subject><subject>Single crystals</subject><subject>Small angle X ray scattering</subject><subject>Speciation</subject><subject>Thermal analysis</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpFkM1KAzEUhYMoWKsbnyDoThi9N38zWZbBX6R1UXAhEtI0wantZJzMLPoGrn1En8SRCq7O4fBxuPcQcopwicD1VamnD4Aa8nKPjJArnWmmcH_wKEQGUqhDcpTSCgAxVzgik2kVF1W_oX3T2XdPF1tq6csTLegzFQWdUSwEfaUCvj-_6Ma6NrqtW1eONnG9tXUV62NyEOw6-ZM_HZP5zfW8vMseZ7f35eQxc8hRZEEvrbWFKxRbeMaV0lIHkA5hKWQIWISQO6sUz0Fb9Mwx5rjLvciHkAEfk7NdbUxdZZKrOu_eXKxr7zqDkkkJcoDOd1DTxo_ep86sYt_Ww1mGMaGAAzAxUBc7avgmpdYH07TVxrZbg2B-ZzT_M_IfJUtghw</recordid><startdate>20190624</startdate><enddate>20190624</enddate><creator>Shmakova, Alexandra A.</creator><creator>Volchek, Victoria V.</creator><creator>Yanshole, Vadim</creator><creator>Kompankov, Nikolay B.</creator><creator>Martin, Nicolas P.</creator><creator>Nyman, May</creator><creator>Abramov, Pavel A.</creator><creator>Sokolov, Maxim N.</creator><general>Royal Society of Chemistry</general><general>Royal Society of Chemistry (RSC)</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-1787-0518</orcidid><orcidid>https://orcid.org/0000-0003-4479-5100</orcidid><orcidid>https://orcid.org/0000-0003-1693-2323</orcidid><orcidid>https://orcid.org/0000-0003-1512-3049</orcidid><orcidid>https://orcid.org/0000-0001-9361-4594</orcidid><orcidid>https://orcid.org/0000000344795100</orcidid><orcidid>https://orcid.org/0000000193614594</orcidid><orcidid>https://orcid.org/0000000316932323</orcidid><orcidid>https://orcid.org/0000000315123049</orcidid><orcidid>https://orcid.org/0000000217870518</orcidid></search><sort><creationdate>20190624</creationdate><title>Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion</title><author>Shmakova, Alexandra A. ; Volchek, Victoria V. ; Yanshole, Vadim ; Kompankov, Nikolay B. ; Martin, Nicolas P. ; Nyman, May ; Abramov, Pavel A. ; Sokolov, Maxim N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1314-f9daaa8c862be2366959f05c10d45ff18ff7ca663709a1e2c22c3c7e47a66203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aqueous solutions</topic><topic>Atomic beam spectroscopy</topic><topic>Chemical analysis</topic><topic>Crystallography</topic><topic>Emission analysis</topic><topic>Gravimetric analysis</topic><topic>Inductively coupled plasma</topic><topic>Niobium oxides</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Polyelectrolytes</topic><topic>Single crystals</topic><topic>Small angle X ray scattering</topic><topic>Speciation</topic><topic>Thermal analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shmakova, Alexandra A.</creatorcontrib><creatorcontrib>Volchek, Victoria V.</creatorcontrib><creatorcontrib>Yanshole, Vadim</creatorcontrib><creatorcontrib>Kompankov, Nikolay B.</creatorcontrib><creatorcontrib>Martin, Nicolas P.</creatorcontrib><creatorcontrib>Nyman, May</creatorcontrib><creatorcontrib>Abramov, Pavel A.</creatorcontrib><creatorcontrib>Sokolov, Maxim N.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><collection>OSTI.GOV</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shmakova, Alexandra A.</au><au>Volchek, Victoria V.</au><au>Yanshole, Vadim</au><au>Kompankov, Nikolay B.</au><au>Martin, Nicolas P.</au><au>Nyman, May</au><au>Abramov, Pavel A.</au><au>Sokolov, Maxim N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion</atitle><jtitle>New journal of chemistry</jtitle><date>2019-06-24</date><risdate>2019</risdate><volume>43</volume><issue>25</issue><spage>9943</spage><epage>9952</epage><pages>9943-9952</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>Reactions of inorganic macrocyclic polytungstate cavitands K
28
Li
5
H
7
[P
8
W
48
O
184
]·92H
2
O or Li
17
(NH
4
)
21
H
2
[P
8
W
48
O
184
]·85H
2
O with (NH
4
)[NbO(C
2
O
4
)
2
(H
2
O)
2
]·3H
2
O (Nb–Ox) in aqueous solution lead to incorporation of up to five {NbO(H
2
O)}
3+
units into the {P
8
W
48
} cavity. The most stable species contain four {NbO(H
2
O)}
3+
units. The uptake of {NbO(H
2
O)}
3+
was determined by corroborative methods including single crystal XRD, inductively coupled plasma atomic emission spectroscopy (ICP-AES),
31
P and
13
C nuclear magnetic resonance (NMR), C–H–N elemental analysis (EA) and thermal gravimetric analysis (TGA). Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and small angle X-ray scattering (SAXS).</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/C9NJ01907C</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-1787-0518</orcidid><orcidid>https://orcid.org/0000-0003-4479-5100</orcidid><orcidid>https://orcid.org/0000-0003-1693-2323</orcidid><orcidid>https://orcid.org/0000-0003-1512-3049</orcidid><orcidid>https://orcid.org/0000-0001-9361-4594</orcidid><orcidid>https://orcid.org/0000000344795100</orcidid><orcidid>https://orcid.org/0000000193614594</orcidid><orcidid>https://orcid.org/0000000316932323</orcidid><orcidid>https://orcid.org/0000000315123049</orcidid><orcidid>https://orcid.org/0000000217870518</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2019-06, Vol.43 (25), p.9943-9952 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1525505 |
| source | Royal Society of Chemistry |
| subjects | Aqueous solutions Atomic beam spectroscopy Chemical analysis Crystallography Emission analysis Gravimetric analysis Inductively coupled plasma Niobium oxides NMR Nuclear magnetic resonance Polyelectrolytes Single crystals Small angle X ray scattering Speciation Thermal analysis |
| title | Niobium uptake by a [P 8 W 48 O 184 ] 40− macrocyclic polyanion |
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