A new synthetic route to in-chain metallopolymers via copper(i) catalyzed azide-platinum-acetylide iClick

The first example of an in-chain metallo-poly(triazolate) synthesized by CuAAC is reported. Azido-platinum-acetylide (A-M-B) monomers are catalytically polymerized with copper(i) acetate to yield 1,2,3-triazolate linked Pt(ii) units. The metallopolymers are characterized by multinuclear NMR, IR, UV/...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (71), p.9934-9937
Main Authors: Beto, C C, Holt, E D, Yang, Y, Ghiviriga, I, Schanze, K S, Veige, A S
Format: Article
Language:English
Subjects:
Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The first example of an in-chain metallo-poly(triazolate) synthesized by CuAAC is reported. Azido-platinum-acetylide (A-M-B) monomers are catalytically polymerized with copper(i) acetate to yield 1,2,3-triazolate linked Pt(ii) units. The metallopolymers are characterized by multinuclear NMR, IR, UV/Vis, GPC, and MS.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc06289c