Enhanced outcoupling in flexible organic light-emitting diodes on scattering polyimide substrates

• Published in: Organic electronics 2017-12, Vol.51, p.471-476
• Main Authors: Lee, Kyung Min, Fardel, Romain, Zhao, Lianfeng, Arnold, Craig B., Rand, Barry P.
• Format: Article
• Language: English
• Subjects: Colorless polyimide; ENGINEERING; Flexible organic light-emitting diodes; Outcoupling; Scattering substrate; Silver nanowires; White organic light emitting devices
• ISSN: 1566-1199; 1878-5530
• DOI: 10.1016/j.orgel.2017.09.042

We demonstrate an upscalable approach to increase outcoupling in organic light-emitting diodes (OLEDs) fabricated on flexible substrates. The outcoupling enhancement is enabled by introducing a thin film of microporous polyimide on the backside of silver nanowire (AgNW) electrodes embedded in neat colorless polyimide. This porous polyimide film, prepared by immersion precipitation, utilizes a large index contrast between the polyimide host and randomly distributed air voids, resulting in broadband haze (>75%). In addition, the composite polyimide/AgNW scattering substrate inherits the high thermal (>360 °C), chemical, and mechanical stability of polyimides. The outcoupling efficiency of the composite scattering substrate is studied via optical characterization of the composite substrate and electron microscopy of the scattering film. The flexible scattering substrates compared to glass/indium tin oxide (ITO) allows for a 74% enhancement in external quantum efficiency (EQE) for a phosphorescent green OLED, and 68% EQE enhancement for a phosphorescent white OLED. The outcoupling enhancement remains unharmed after 5000 bending cycles at a 2 mm bending radius. Moreover, the color uniformity over viewing angles is improved, an important feature for lighting applications. [Display omitted] •Porous scattering films are obtained by immersion precipitation of colorless polyimide for flexible substrate loss recovery.•The porous scattering films are applied to the flexible substrate backside of silver nanowires in neat colorless polyimide.•The scattering devices allow for 74% and 68% increase in EQE for green and white OLEDs, respectively, compared to glass/ITO.•The outcoupling efficiency of the porous scattering films remains unharmed after 5000 cycles at 2 mm bending radius.