Bi 3 (PO 4 )O 3 , the Simplest Bismuth(III) Oxophosphate: Synthesis, IR Spectroscopy, Crystal Structure, and Structural Complexity

The bismuth(III) oxophosphate Bi (PO )O was obtained by hydrothermal synthesis. The unit cell has a = 5.6840(6) Å, b = 7.0334(7) Å, c = 9.1578(9) Å, α = 78.958(2)°, β = 77.858(2)°, γ = 68.992(2)°, V = 331.41(6) Å , space group P1̅, and Z = 2. The crystal chemical formula that reflects the presence o...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry 2018-06, Vol.57 (12), p.6799-6802
Main Authors: Aksenov, Sergey M, Yamnova, Natalia A, Borovikova, Elena Yu, Volkov, Anatoly S, Ksenofontov, Dmitry A, Dimitrova, Olga V, Gurbanova, Olga A, Deyneko, Dina V, Dal Bo, Fabrice, Burns, Peter C
Format: Article
Language:English
Subjects:
Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The bismuth(III) oxophosphate Bi (PO )O was obtained by hydrothermal synthesis. The unit cell has a = 5.6840(6) Å, b = 7.0334(7) Å, c = 9.1578(9) Å, α = 78.958(2)°, β = 77.858(2)°, γ = 68.992(2)°, V = 331.41(6) Å , space group P1̅, and Z = 2. The crystal chemical formula that reflects the presence of oxo-centered tetrahedra and triangles is [O O Bi ](PO ). The crystal structure contains [O Bi ] -heteropolyhedral corrugated layers parallel to (001), which alternate along [001] with isolated (PO ) tetrahedra. The structural complexity parameters are v = 22 atoms, I = 3.459 bits/atoms, and I = 76.107 bits/unit cell, and thus Bi (PO )O is the simplest pure bismuth(III) oxophosphate.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.8b01195