Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals

Perovskite-phase cesium bismuth halide (Cs3Bi2X9; X= Cl, Br, I) nanocrystals were synthesized using a hot-injection approach. These nanocrystals adopted ordered-vacancy perovskite crystal structures and demonstrated composition-tunable optical properties. Growth occurred by initial formation of Bi0...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2018-03, Vol.54 (29)
Main Authors: Nelson, R. D., Santra, K., Wang, Y., Hadi, A., Petrich, J. W., Panthani, M. G.
Format: Article
Language:English
Subjects:
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page
container_issue 29
container_start_page
container_title Chemical communications (Cambridge, England)
container_volume 54
creator Nelson, R. D.
Santra, K.
Wang, Y.
Hadi, A.
Petrich, J. W.
Panthani, M. G.
description Perovskite-phase cesium bismuth halide (Cs3Bi2X9; X= Cl, Br, I) nanocrystals were synthesized using a hot-injection approach. These nanocrystals adopted ordered-vacancy perovskite crystal structures and demonstrated composition-tunable optical properties. Growth occurred by initial formation of Bi0 seeds, and morphology was controlled by precursor and seed concentration. The Cs3Bi2I9 nanocrystals demonstrated excellent stability under ambient conditions for several months. Contrary to previous reports, we find that photoluminescence originates from the precursor material as opposed to the perovskite nanocrystals.
format article
fullrecord <record><control><sourceid>osti</sourceid><recordid>TN_cdi_osti_scitechconnect_1556931</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1556931</sourcerecordid><originalsourceid>FETCH-osti_scitechconnect_15569313</originalsourceid><addsrcrecordid>eNqNjM0KgkAUhYcoyH7e4dJeSHRM11G0r0W7mK5XnNIZmTsKvn0T9ACdzXfg_MxElKR5FsusuM-_XpbxIc3kUqyYX_ugRBaRUNfJ-IZYMyhTge29RtVC72xPzmtisDVYV5GjKh4VKoMThMiO_NaeAMN06OCpuRt8A41qdUVglLHoJvaq5Y1Y1AG0_XEtdufT7XiJLXv9YAwv2KA1htA_EinzMk3Sv0ofwZRIOA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Nelson, R. D. ; Santra, K. ; Wang, Y. ; Hadi, A. ; Petrich, J. W. ; Panthani, M. G.</creator><creatorcontrib>Nelson, R. D. ; Santra, K. ; Wang, Y. ; Hadi, A. ; Petrich, J. W. ; Panthani, M. G. ; Ames Laboratory (AMES), Ames, IA (United States)</creatorcontrib><description>Perovskite-phase cesium bismuth halide (Cs3Bi2X9; X= Cl, Br, I) nanocrystals were synthesized using a hot-injection approach. These nanocrystals adopted ordered-vacancy perovskite crystal structures and demonstrated composition-tunable optical properties. Growth occurred by initial formation of Bi0 seeds, and morphology was controlled by precursor and seed concentration. The Cs3Bi2I9 nanocrystals demonstrated excellent stability under ambient conditions for several months. Contrary to previous reports, we find that photoluminescence originates from the precursor material as opposed to the perovskite nanocrystals.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><language>eng</language><publisher>United States: Royal Society of Chemistry</publisher><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><ispartof>Chemical communications (Cambridge, England), 2018-03, Vol.54 (29)</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000000237952051 ; 0000000225561889</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1556931$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Nelson, R. D.</creatorcontrib><creatorcontrib>Santra, K.</creatorcontrib><creatorcontrib>Wang, Y.</creatorcontrib><creatorcontrib>Hadi, A.</creatorcontrib><creatorcontrib>Petrich, J. W.</creatorcontrib><creatorcontrib>Panthani, M. G.</creatorcontrib><creatorcontrib>Ames Laboratory (AMES), Ames, IA (United States)</creatorcontrib><title>Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals</title><title>Chemical communications (Cambridge, England)</title><description>Perovskite-phase cesium bismuth halide (Cs3Bi2X9; X= Cl, Br, I) nanocrystals were synthesized using a hot-injection approach. These nanocrystals adopted ordered-vacancy perovskite crystal structures and demonstrated composition-tunable optical properties. Growth occurred by initial formation of Bi0 seeds, and morphology was controlled by precursor and seed concentration. The Cs3Bi2I9 nanocrystals demonstrated excellent stability under ambient conditions for several months. Contrary to previous reports, we find that photoluminescence originates from the precursor material as opposed to the perovskite nanocrystals.</description><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqNjM0KgkAUhYcoyH7e4dJeSHRM11G0r0W7mK5XnNIZmTsKvn0T9ACdzXfg_MxElKR5FsusuM-_XpbxIc3kUqyYX_ugRBaRUNfJ-IZYMyhTge29RtVC72xPzmtisDVYV5GjKh4VKoMThMiO_NaeAMN06OCpuRt8A41qdUVglLHoJvaq5Y1Y1AG0_XEtdufT7XiJLXv9YAwv2KA1htA_EinzMk3Sv0ofwZRIOA</recordid><startdate>20180313</startdate><enddate>20180313</enddate><creator>Nelson, R. D.</creator><creator>Santra, K.</creator><creator>Wang, Y.</creator><creator>Hadi, A.</creator><creator>Petrich, J. W.</creator><creator>Panthani, M. G.</creator><general>Royal Society of Chemistry</general><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000000237952051</orcidid><orcidid>https://orcid.org/0000000225561889</orcidid></search><sort><creationdate>20180313</creationdate><title>Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals</title><author>Nelson, R. D. ; Santra, K. ; Wang, Y. ; Hadi, A. ; Petrich, J. W. ; Panthani, M. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_15569313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nelson, R. D.</creatorcontrib><creatorcontrib>Santra, K.</creatorcontrib><creatorcontrib>Wang, Y.</creatorcontrib><creatorcontrib>Hadi, A.</creatorcontrib><creatorcontrib>Petrich, J. W.</creatorcontrib><creatorcontrib>Panthani, M. G.</creatorcontrib><creatorcontrib>Ames Laboratory (AMES), Ames, IA (United States)</creatorcontrib><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nelson, R. D.</au><au>Santra, K.</au><au>Wang, Y.</au><au>Hadi, A.</au><au>Petrich, J. W.</au><au>Panthani, M. G.</au><aucorp>Ames Laboratory (AMES), Ames, IA (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2018-03-13</date><risdate>2018</risdate><volume>54</volume><issue>29</issue><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Perovskite-phase cesium bismuth halide (Cs3Bi2X9; X= Cl, Br, I) nanocrystals were synthesized using a hot-injection approach. These nanocrystals adopted ordered-vacancy perovskite crystal structures and demonstrated composition-tunable optical properties. Growth occurred by initial formation of Bi0 seeds, and morphology was controlled by precursor and seed concentration. The Cs3Bi2I9 nanocrystals demonstrated excellent stability under ambient conditions for several months. Contrary to previous reports, we find that photoluminescence originates from the precursor material as opposed to the perovskite nanocrystals.</abstract><cop>United States</cop><pub>Royal Society of Chemistry</pub><orcidid>https://orcid.org/0000000237952051</orcidid><orcidid>https://orcid.org/0000000225561889</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2018-03, Vol.54 (29)
issn 1359-7345
1364-548X
language eng
recordid cdi_osti_scitechconnect_1556931
source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
title Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T05%3A20%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-osti&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20optical%20properties%20of%20ordered-vacancy%20perovskite%20cesium%20bismuth%20halide%20nanocrystals&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Nelson,%20R.%20D.&rft.aucorp=Ames%20Laboratory%20(AMES),%20Ames,%20IA%20(United%20States)&rft.date=2018-03-13&rft.volume=54&rft.issue=29&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/&rft_dat=%3Costi%3E1556931%3C/osti%3E%3Cgrp_id%3Ecdi_FETCH-osti_scitechconnect_15569313%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true