Iodine immobilization by silver-impregnated granular activated carbon in cementitious systems

Silver (Ag)-based technologies are amongst the most common approaches to removing radioiodine from aqueous waste streams. As a result, a large worldwide inventory of radioactive AgI waste presently exits, which must be stabilized for final disposition. In this work, the efficacy of silver-impregnate...

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Bibliographic Details
Published in:Journal of environmental radioactivity 2019-07, Vol.208-209 (C)
Main Authors: Li, Dien, Kaplan, Daniel I., Price, Kimberly A., Seaman, John C., Roberts, Kimberly, Xu, Chen, Lin, Peng, Xing, Wei, Schwehr, Kathleen, Santschi, Peter H.
Format: Article
Language:English
Subjects:
cement
ENVIRONMENTAL SCIENCES
immobilization
iodine speciation
redox
silver-impregnated granulated activated carbon
slag
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Summary:Silver (Ag)-based technologies are amongst the most common approaches to removing radioiodine from aqueous waste streams. As a result, a large worldwide inventory of radioactive AgI waste presently exits, which must be stabilized for final disposition. In this work, the efficacy of silver-impregnated granular activated carbon (Ag-GAC) to remove iodide (I-), iodate (IO3-) and organo-iodine (org-I) from cementitious leachate was examined. In addition, cementitious materials containing I-, IO3-, or org-I loaded Ag-GAC were characterized by iodine K-edge XANES and EXAFS to provide insight into iodine stability and speciation in these waste forms. The Ag-GAC was very effective at removing I- and org-I, but ineffective at removing IO3- from slag-free grout leachate under oxic conditions. I- or org-I removal was due to the formation of insoluble AgI(s) or Ag-org-I(s) on the Ag-GAC. When I--loaded Ag-GAC material was cured with slag-free and slag grouts, I- was released from AgI(s) to form a hydrated I- species. Conversely, when org-I loaded Ag-GAC material was cured in the two grout formulations, no change was observed in the iodine speciation, indicating the org-I species remained bound to the Ag. Because little IO3- was bound to the Ag-GAC, it was not detectable in the grout. Thus, grout formulation and I speciation in the waste stream can significantly influence the effectiveness of the long-term disposal of radioiodine associated with Ag-GAC in grout waste forms.
ISSN:0265-931X
DOI:10.1016/j.jenvrad.2019.106017