Additional complexity in the Raman spectra of U3O8

• Published in: Journal of nuclear materials 2019-12, Vol.527 (C), p.151790, Article 151790
• Main Authors: Miskowiec, A., Niedziela, J.L., Spano, T.L., Ambrogio, M.W., Finkeldei, S., Hunt, R., Shields, A.E.
• Format: Article
• Language: English
• Subjects: Chemical analysis; Crystal defects; Crystal lattices; Crystal structure; Organic chemistry; Oxides; Oxygen content; RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; Raman spectra; Raman spectroscopy; Spectroscopy; Spectrum analysis; U3O8; Uranium; Uranium dioxide; Uranium oxides
• ISSN: 0022-3115; 1873-4820
• DOI: 10.1016/j.jnucmat.2019.151790

Uranium oxides are readily amenable to investigation using Raman spectroscopy, and this technique is frequently used as a chemical analysis tool. We show, in triuranium octoxide (U3O8), the presence of previously unreported Raman peaks located below 100 cm−1. By maximum intensity, the strongest peak in U3O8 appears at 54 cm−1 and is resolution limited, making this mode an ideal candidate for chemically identifying U3O8 using Raman spectroscopy. Detailed peak analysis indicates that the main spectral feature between 300 and 500 cm−1 is more accurately described by a septet than a triplet. Two samples of differing oxygen content show only minor differences in bulk crystal structure, but subtle changes in lattice dynamics are suggestive of defect scattering in analogy to UO2+x. [Display omitted] •U3O8 has strong, low-energy Raman-active modes.•Defect driven phonon lifetime suppression may be present in U3O8.•Detailed peak fitting analysis may suggest subtle differences in spectra correlated with oxidation.