Pressure-induced inclusion of neon in the crystal structure of a molecular Cu 2 (pacman) complex at 4.67 GPa

Crystals of a Cu complex of the macrocyclic Schiff-base calixpyrrole or 'Pacman' ligand, Cu (L), do not contain any solvent-accessible void space at ambient pressure, but adsorb neon at 4.67 GPa, forming Cu (L)·3.5Ne.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-03, Vol.56 (23), p.3449-3452
Main Authors: Giordano, Nico, Beavers, Christine M, Kamenev, Konstantin V, Love, Jason B, Pankhurst, James R, Teat, Simon J, Parsons, Simon
Format: Article
Language:English
Subjects:
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Summary:Crystals of a Cu complex of the macrocyclic Schiff-base calixpyrrole or 'Pacman' ligand, Cu (L), do not contain any solvent-accessible void space at ambient pressure, but adsorb neon at 4.67 GPa, forming Cu (L)·3.5Ne.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc09884d