Correction to “Quantifying the σ and π Interactions between U(V) f Orbitals and Halide, Alkyl, Alkoxide, Amide and Ketimide Ligands”

While preparing a follow-up manuscript, we found an error in one of the orbital reduction factors used in our crystal field models, given in Scheme 2. The third equation in that scheme was published as ka2t2 = 1 - 12 N2 2 a'p ; however, the correct formula is k a2t2 = 1 - 12 N'a'p2. (...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2020-03, Vol.142 (11), p.5442-5445
Main Authors: Lukens, Wayne W, Edelstein, Norman M, Magnani, Nicola, Hayton, Trevor W, Fortier, Skye, Seaman, Lani A
Format: Article
Language:English
Online Access:Get full text
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Summary:While preparing a follow-up manuscript, we found an error in one of the orbital reduction factors used in our crystal field models, given in Scheme 2. The third equation in that scheme was published as ka2t2 = 1 - 12 N2 2 a'p ; however, the correct formula is k a2t2 = 1 - 12 N'a'p2. (Table Presented).
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.0c02284