Synthesis of atomically precise single-crystalline Ru 2 -based coordination polymers

Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal–organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization of ki...

Full description

Saved in:
Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2020-11, Vol.49 (45), p.16077-16081
Main Authors: Gao, Wen-Yang, Van Trieste III, Gerard Pierre, Powers, David C.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal–organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization of kinetically inert Ru 2 metallomonomers via labile Ag–N bonds provides access to a family of atomically precise single-crystalline Ru 2 -based coordination polymers with varied network topology and primary coordination sphere.
ISSN:1477-9226
1477-9234
DOI:10.1039/D0DT02233K