Photoionization of C4H5 Isomers

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2020-07, Vol.124 (29), p.6050-6060
• Main Authors: Hartweg, S, Loison, J.-C, Boyé-Péronne, S, Gans, B, Holland, D. M. P, Garcia, G. A, Nahon, L, Pratt, S. T
• Format: Article
• Language: English
• Subjects: A: Spectroscopy, Molecular Structure, and Quantum Chemistry; Chemical Physics; Chemical structure; energy; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; molecular structure; photoionization; Physics; precursors
• ISSN: 1089-5639; 1520-5215
• DOI: 10.1021/acs.jpca.0c03317

Single-photon, photoelectron–photoion coincidence spectroscopy is used to record the mass-selected ion spectra and slow photoelectron spectra of C4H5 radicals produced by the abstraction of hydrogen atoms from three C4H6 precursors by fluorine atoms generated by a microwave discharge. Three different C4H5 isomers are identified, with the relative abundances depending on the nature of the precursor (1-butyne, 1,2-butadiene, and 1,3-butadiene). The results are compared with our previous work using 2-butyne as a precursor [ Hrodmarsson, H. R. J. Phys. Chem. A 2019, 123, 1521−1528 ]. The slow photoelectron spectra provide new information on the three radical isomers that is in good agreement with previous experimental and theoretical results [ Lang, M. J. Phys. Chem. A 2015, 119, 3995−4000 ; Hansen, N. J. Phys. Chem. A 2006, 110, 3670–3678 ]. The energy scans of the C4H5 photoionization signal are recorded with substantially better resolution and signal-to-noise ratio than those in earlier work, allowing the observation of autoionizing resonances based on excited states of the C4H5 cation. Photoelectron images recorded at several energies are also reported, providing insight into the decay processes of these excited states. Finally, in contrast to the earlier work using 2-butyne as a precursor, where H-atom abstraction was the only observed process, F- and H-atom additions to the present precursors are also observed through the detection of C4H6F, C4H5F, and C4H7.