Evaluation of analytical performance of double pulse laser-induced breakdown spectroscopy for the detection of rare earth elements

•Double pulse LIBS for REE study.•Signal enhancement with double pulse LIBS.•Significant effect of inter-pulse delay in double LIBS for REE.•Large improvement in LOD of REE. Double pulse laser-induced breakdown spectroscopy (DP-LIBS) in collinear configuration was demonstrated to enhance the signal...

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Bibliographic Details
Published in:Optics and laser technology 2020-06, Vol.126 (C), p.106110, Article 106110
Main Authors: Bhatt, Chet R., Hartzler, Daniel, Jain, Jinesh C., McIntyre, Dustin L.
Format: Article
Language:English
Subjects:
Chemical properties
Emission spectra
Europium compounds
Gadolinium
Gadolinium oxides
Laser induced breakdown spectroscopy
Lasers
Praseodymium oxide
Rare earth elements
Spectrum analysis
Trace elements
Yttrium
Yttrium oxide
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Summary:•Double pulse LIBS for REE study.•Signal enhancement with double pulse LIBS.•Significant effect of inter-pulse delay in double LIBS for REE.•Large improvement in LOD of REE. Double pulse laser-induced breakdown spectroscopy (DP-LIBS) in collinear configuration was demonstrated to enhance the signal intensity of three rare earth elements (REEs), Eu, Gd, Pr, and Y (Yttrium is included because of its similar chemical properties and occurrence in similar deposits as REE). Significant enhancement in spectral signals of all elements was observed with an aid of second laser. Two laser pulses of 1064 nm wavelength were employed in collinear geometry on the Pr2O3, Eu2O3, Gd2O3, and Y2O3 pellets to obtain emission spectra. For selected strong emission lines of Eu and Gd signal enhancement was found to be 3–7-fold and that for Y and Pr lines was observed to be 3–13-fold compared to single-pulse laser-induced breakdown spectroscopy (SP-LIBS). Role of inter-pulse delay between two pulses in DP-LIBS was found to be very crucial. While comparing selected ionic and neutral lines, ionic lines were found to have larger signal enhancement in DP-LIBS at the experimental conditions used in this study.
ISSN:0030-3992
1879-2545
DOI:10.1016/j.optlastec.2020.106110