Metastability of diamond ramp-compressed to 2 terapascals

• Published in: Nature (London) 2021-01, Vol.589 (7843), p.532-535
• Main Authors: Lazicki, A., McGonegle, D., Rygg, J. R., Braun, D. G., Swift, D. C., Gorman, M. G., Smith, R. F., Heighway, P. G., Higginbotham, A., Suggit, M. J., Fratanduono, D. E., Coppari, F., Wehrenberg, C. E., Kraus, R. G., Erskine, D., Bernier, J. V., McNaney, J. M., Rudd, R. E., Collins, G. W., Eggert, J. H., Wark, J. S.
• Format: Article
• Language: English
• Subjects: 639/301/119/1002; 639/33/445/862; 639/766/119/1002; 704/445/862; Ablation; Allotropy; Analysis; Atmospheric models; Atmospheric pressure; Bonding strength; Carbon; Carbon allotropes; Chemical bonds; Compressibility; CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Diamond crystals; Diamonds; Earth core; Exoplanets; Extrasolar planets; Fullerenes; Graphite; Humanities and Social Sciences; Identification and classification; Laboratories; Measurement; Mechanical properties; Metastability; Molecular orbitals; multidisciplinary; Predictions; Science; Science (multidisciplinary); Structure; Structure of solids and liquids; Velocity; X-ray diffraction; X-rays
• ISSN: 0028-0836; 1476-4687
• DOI: 10.1038/s41586-020-03140-4

Carbon is the fourth-most prevalent element in the Universe and essential for all known life. In the elemental form it is found in multiple allotropes, including graphite, diamond and fullerenes, and it has long been predicted that even more structures can exist at pressures greater than those at Earth’s core 1 – 3 . Several phases have been predicted to exist in the multi-terapascal regime, which is important for accurate modelling of the interiors of carbon-rich exoplanets 4 , 5 . By compressing solid carbon to 2 terapascals (20 million atmospheres; more than five times the pressure at Earth’s core) using ramp-shaped laser pulses and simultaneously measuring nanosecond-duration time-resolved X-ray diffraction, we found that solid carbon retains the diamond structure far beyond its regime of predicted stability. The results confirm predictions that the strength of the tetrahedral molecular orbital bonds in diamond persists under enormous pressure, resulting in large energy barriers that hinder conversion to more-stable high-pressure allotropes 1 , 2 , just as graphite formation from metastable diamond is kinetically hindered at atmospheric pressure. This work nearly doubles the highest pressure at which X-ray diffraction has been recorded on any material. X-ray diffraction measurements of solid carbon compressed to pressures of about two terapascals (approximately twenty million atmospheres) find that carbon retains a diamond structure even under these extreme conditions.