Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys

The microstructures, mechanical, corrosion, and wear behaviors of the TixZrNbTaMo (x = 0.5, 1, 1.5, and 2, molar ratio) high entropy alloys (HEAs) were studied. It was found that the Ti–Zr–Nb–Ta–Mo HEAs showed a dendrite structure with two body-centered-cubic (BCC) solid solution phases. The Ti0.5Zr...

Full description

Saved in:
Bibliographic Details
Published in:Journal of alloys and compounds 2021-04, Vol.861 (1), p.157997, Article 157997
Main Authors: Hua, Nengbin, Wang, Wenjie, Wang, Qianting, Ye, Youxiong, Lin, Sihan, Zhang, Lei, Guo, Qiaohang, Brechtl, Jamieson, Liaw, Peter K.
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The microstructures, mechanical, corrosion, and wear behaviors of the TixZrNbTaMo (x = 0.5, 1, 1.5, and 2, molar ratio) high entropy alloys (HEAs) were studied. It was found that the Ti–Zr–Nb–Ta–Mo HEAs showed a dendrite structure with two body-centered-cubic (BCC) solid solution phases. The Ti0.5ZrNbTaMo HEA exhibited a high hardness of about 500 HV, high compressive strength approaching 2,600 MPa, and large plastic strain of over 30%. Furthermore, the highly-protective oxide films formed on the surface of Ti–Zr–Nb–Ta–Mo HEAs in the phosphate buffer saline (PBS) solution, which resulted in the high corrosion resistance of the HEAs. The Ti–Zr–Nb–Ta–Mo HEAs exhibited the greater dry- and wet-wear resistance than that of the traditional biomedical Ti6Al4V alloy. The results also indicated that with the decrease in the Ti content, the wear resistance of the Ti–Zr–Nb–Ta–Mo HEAs in the PBS solution improved. Finally, the Ti0.5ZrNbTaMo alloy presented the highest corrosive wear resistance among the four HEAs owing to its combination of good mechanical properties and high chemical stability. ∙Ti–Zr–Nb–Ta–Mo HEAs show a dendrite structure with two BCC solid solution phases.∙The Ti0.5ZrNbTaMo HEA exhibits the high strength, hardness, and good plasticity.∙The HEAs possess the better corrosion property than that of Ti6Al4V.∙The dry- and corrosive-wear resistance of the HEAs is superior to that of Ti6Al4V.∙The Ti0.5ZrNbTaMo shows the best corrosive wear resistance among the four HEAs.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2020.157997