Depolymerization of Lignin into Monophenolics by Ferrous/Persulfate Reagent under Mild Conditions

This study aimed to use a persulfate together with transition metal ions as the reagent to effectively depolymerize lignin into monophenolic compounds under mild conditions (ambient pressure, temperature

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Bibliographic Details
Published in:ChemSusChem 2020-12, Vol.13 (24), p.6582-6593
Main Authors: Bao, Hanxi, Sagues, William J., Wang, Yigui, Peng, Wenbo, Zhang, Lin, Yang, Shunchang, Xiao, Dequan, Tong, Zhaohui
Format: Article
Language:English
Subjects:
Box-Behnken model
Density functional theory
Depolymerization
Design of experiments
Dimers
free radical reaction
Free radicals
Hydroxyl radicals
Lignin
lignin depolymerization
Liquid chromatography
NMR spectroscopy
phenolic monomers
Pressure
Quantum chemistry
Reagents
Response surface methodology
Transition metals
β-O-4 cleavage
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Description
Summary:This study aimed to use a persulfate together with transition metal ions as the reagent to effectively depolymerize lignin into monophenolic compounds under mild conditions (ambient pressure, temperature
ISSN:1864-5631
1864-564X
DOI:10.1002/cssc.202002240