One electron reduction transforms high-valent low-spin cobalt alkylidene into high-spin cobalt( ii ) carbene radical

Synthesis, electronic structure, and reactivity of a novel Co(ii) carbene radical in the bis(alkoxide) ligand environment are reported.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-01, Vol.56 (60)
Main Authors: Grass, Amanda, Bellow, James A., Morrison, Gregory, zur Loye, Hans-Conrad, Lord, Richard L., Groysman, Stanislav
Format: Article
Language:English
Subjects:
Chemistry
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Summary:Synthesis, electronic structure, and reactivity of a novel Co(ii) carbene radical in the bis(alkoxide) ligand environment are reported.
ISSN:1359-7345
1364-548X