One electron reduction transforms high-valent low-spin cobalt alkylidene into high-spin cobalt( ii ) carbene radical

Synthesis, electronic structure, and reactivity of a novel Co(ii) carbene radical in the bis(alkoxide) ligand environment are reported.

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Published in:Chemical communications (Cambridge, England) England), 2020-01, Vol.56 (60)
Main Authors: Grass, Amanda, Bellow, James A., Morrison, Gregory, zur Loye, Hans-Conrad, Lord, Richard L., Groysman, Stanislav
Format: Article
Language:English
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Chemistry
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container_issue 60
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container_title Chemical communications (Cambridge, England)
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creator Grass, Amanda
Bellow, James A.
Morrison, Gregory
zur Loye, Hans-Conrad
Lord, Richard L.
Groysman, Stanislav
description Synthesis, electronic structure, and reactivity of a novel Co(ii) carbene radical in the bis(alkoxide) ligand environment are reported.
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1364-548X
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Chemistry
title One electron reduction transforms high-valent low-spin cobalt alkylidene into high-spin cobalt( ii ) carbene radical
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