Synthesis and Electrical Properties of a New Compound (BiSe)0.97(Bi2Se3)1.26(BiSe)0.97(MoSe2) Containing Metallic 1T-MoSe2

• Published in: Chemistry of materials 2021-08, Vol.33 (16), p.6403-6411
• Main Authors: Choffel, Marisa A, Gannon, Renae N, Göhler, Fabian, Miller, Aaron M, Medlin, Douglas L, Seyller, Thomas, Johnson, David C
• Format: Article
• Language: English
• Subjects: Deposition; Diffraction; Heterostructures; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Layers; Precursors
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/acs.chemmater.1c01623

The synthesis and electrical properties of a new misfit compound containing BiSe, Bi2Se3, and MoSe2 constituent layers are reported. The reaction pathway involves competition between the formation of (BiSe)1+x (Bi2Se3)1+y (BiSe)1+x (MoSe2) and [(Bi2Se3)1+y ]2(MoSe2). Excess Bi and Se are required in the precursor to synthesize (BiSe)1+x (Bi2Se3)1+y (BiSe)1+x (MoSe2). High-angle annular dark field-scanning transmission electron microscopy (HAADF-STEM) confirm the stacking sequence of the heterostructure. Small grains of both 2H- and 1T-MoSe2 are observed in the MoSe2 layers. X-ray photoelectron spectroscopy (XPS) indicates that there is a significantly higher percentage of 1T-MoSe2 in (BiSe)1+x (Bi2Se3)1+y (BiSe)1+x (MoSe2) than in (BiSe)0.97(MoSe2), suggesting that more charge transfer to MoSe2 occurs due to the additional BiSe layer. The additional charge transfer results in (BiSe)1+x (Bi2Se3)1+y (BiSe)1+x (MoSe2) having a low resistivity (14–19 μΩ m) with metallic temperature dependence. The heterogeneous mix of MoSe2 polytypes observed in the XPS complicates the interpretation of the Hall data as two bands contribute to the electrical continuity.