The effects of Ti content and quenching on phase transformations, microstructures, and mechanical properties in uranium-titanium alloys

• Published in: Journal of nuclear materials 2021-11, Vol.559
• Main Authors: Eckelmeyer, Kenneth H., Romig, A. D., Ludtka, Gerard M., Mackiewicz-Ludtka, Gail, Chapman, Lloyd R.
• Format: Article
• Language: English
• Subjects: Martensite; MATERIALS SCIENCE; Microstructure; Phase transformations; Quenching; Uranium alloys
• ISSN: 0022-3115; 1873-4820

In this work, the effect of Ti content on phase transformations, microstructures, and mechanical properties of U-Ti alloys are described for alloys containing 0.3 wt.% to 2.0 wt.%Ti. Rapid cooling is required to overcome diffusional decomposition of γ-phase and facilitate diffusionless transformation to supersaturated variants of α-phase. Critical cooling rate increases with increasing Ti content, opposite to the trend observed in U-Mo and U-Nb alloys. This difference occurs because the martensite transformation temperatures in these relatively dilute U-Ti alloys are above the knee of the C-curve for diffusional decomposition, unlike those in the more concentrated U-Mo and U-Nb alloys. In these U-Ti alloys critical cooling rate depends on the amount of undercooling required to reach Ms, which increases with increasing Ti content, and the time for diffusional decomposition to occur just above Ms, which decreases with increasing Ti content. The net result is that higher cooling rates are required as Ti content increases. Full quenching results in diffusionless transformation of γ-phase to supersaturated variants of α-phase. Very dilute alloys transform via a γ → β → αm sequence of massive transformations. Martensitic γ → α'a transformation begins at ~0.4%Ti, and 100% α'a microstructures are obtained from ~0.65% to ~1.4% Ti. A transition to banded α'b martensite occurs at ~1.5%Ti. Evidence suggests that the α'a to α'b transition may occur when the cubic γ-phase first transforms to tetragonal γ°, which in turn transforms to orthorhombic α'b via the sequence γ → γ° → α'b. Fully quenched alloys exhibit moderate strengths and ductilities, and their supersaturation with Ti makes them amenable to subsequent age hardening. Subcritical quenching typically results in two-phase microstructures with lower ductilities and near-zero Ti-supersaturation, eliminating the possibility of subsequent age hardening.