Comparative excited state dynamics of metallo meso-(4-fluoro-2,6-dimethyl-phenyl) porphyrins

[Display omitted] •Metalloporphyrin synthesis and structural characterization.•Ultrafast excited state dynamics.•Nonradiative decay kinetics and mechanisms. The Mn(III)Cl and Pd(II) meso-(4-fluoro-2,6-dimethyl-phenyl) porphyrins have been synthesized and structurally characterized by X-ray crystallo...

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Published in:Inorganic chemistry communications 2022-12, Vol.146 (C), p.109999, Article 109999
Main Authors: Crisp, William, Amadis Fagan-Avery, Stephon, Campbell, Brandon M., Morphet, Daniel R., Reynolds, Kristopher G., Kudisch, Bryan, Gonzalez, Miguel I., Zheng, Shao-Liang, Dogutan, Dilek K., Nocera, Daniel G.
Format: Article
Language:English
Subjects:
Excited state dynamics
Laser spectroscopy
Manganese and palladium porphyrins
Picosecond decay
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Summary:[Display omitted] •Metalloporphyrin synthesis and structural characterization.•Ultrafast excited state dynamics.•Nonradiative decay kinetics and mechanisms. The Mn(III)Cl and Pd(II) meso-(4-fluoro-2,6-dimethyl-phenyl) porphyrins have been synthesized and structurally characterized by X-ray crystallography. Together with its Zn(II) congener, this homologous series of porphyrins show the manifestation of d–d states and spin–orbit coupling on the excited state dynamics of metalloporphyrins.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2022.109999