Comparative excited state dynamics of metallo meso-(4-fluoro-2,6-dimethyl-phenyl) porphyrins

[Display omitted] •Metalloporphyrin synthesis and structural characterization.•Ultrafast excited state dynamics.•Nonradiative decay kinetics and mechanisms. The Mn(III)Cl and Pd(II) meso-(4-fluoro-2,6-dimethyl-phenyl) porphyrins have been synthesized and structurally characterized by X-ray crystallo...

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Published in:Inorganic chemistry communications 2022-12, Vol.146 (C), p.109999, Article 109999
Main Authors: Crisp, William, Amadis Fagan-Avery, Stephon, Campbell, Brandon M., Morphet, Daniel R., Reynolds, Kristopher G., Kudisch, Bryan, Gonzalez, Miguel I., Zheng, Shao-Liang, Dogutan, Dilek K., Nocera, Daniel G.
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Language:English
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Excited state dynamics
Laser spectroscopy
Manganese and palladium porphyrins
Picosecond decay
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cited_by cdi_FETCH-LOGICAL-c379t-8a7f612716b0d3e8d6d63e6d96520a55d11e408fa1d083c578bd78d78dbfdf693
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container_issue C
container_start_page 109999
container_title Inorganic chemistry communications
container_volume 146
creator Crisp, William
Amadis Fagan-Avery, Stephon
Campbell, Brandon M.
Morphet, Daniel R.
Reynolds, Kristopher G.
Kudisch, Bryan
Gonzalez, Miguel I.
Zheng, Shao-Liang
Dogutan, Dilek K.
Nocera, Daniel G.
description [Display omitted] •Metalloporphyrin synthesis and structural characterization.•Ultrafast excited state dynamics.•Nonradiative decay kinetics and mechanisms. The Mn(III)Cl and Pd(II) meso-(4-fluoro-2,6-dimethyl-phenyl) porphyrins have been synthesized and structurally characterized by X-ray crystallography. Together with its Zn(II) congener, this homologous series of porphyrins show the manifestation of d–d states and spin–orbit coupling on the excited state dynamics of metalloporphyrins.
doi_str_mv 10.1016/j.inoche.2022.109999
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subjects Excited state dynamics
Laser spectroscopy
Manganese and palladium porphyrins
Picosecond decay
title Comparative excited state dynamics of metallo meso-(4-fluoro-2,6-dimethyl-phenyl) porphyrins
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