Porous but Mechanically Robust All-Inorganic Antireflective Coatings Synthesized using Polymers of Intrinsic Microporosity

• Published in: ACS nano 2022-09, Vol.16 (9), p.14754-14764
• Main Authors: Ji, Cheng, Zhang, Zhongbo, Omotosho, Khalil D., Berman, Diana, Lee, Byeongdu, Divan, Ralu, Guha, Supratik, Shevchenko, Elena V.
• Format: Article
• Language: English
• Subjects: anti-reflective coatings; coating materials; deposition; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; layers; low refractive index; optical coating; optical properties; PIM-1; polymer of intrinsic microporosity; porosity; porous alumina; sequential infiltration synthesis
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.2c05592

Here, we introduce polymer of intrinsic microporosity 1 (PIM-1) to design single-layer and multilayered all-inorganic antireflective coatings (ARCs) with excellent mechanical properties. Using PIM-1 as a template in sequential infiltration synthesis (SIS), we can fabricate highly uniform, mechanically stable conformal coatings of AlO x with porosities of ∼50% and a refractive index of 1.41 compared to 1.76 for nonporous AlO x that is perfectly suited for substrates commonly used in high-end optical systems or touch screens (e.g., sapphire, conductive glass, bendable glass, etc.). We show that such films can be used as a single-layer ARC capable of reduction of the Fresnel reflections of sapphire to as low as 0.1% at 500 nm being deposited only on one side of the substrate. We also demonstrate that deposition of the second layer with higher porosity using block copolymers enables the design of graded-index double-layered coatings. AlO x structures with just two layers and a total thickness of less than 200 nm are capable of reduction of Fresnel reflections under normal illumination to below 0.5% in a broad spectral range with 0.1% reflection at 700 nm. Additionally, and most importantly, we show that highly porous single-layer and graded-index double-layered ARCs are characterized by high hardness and scratch resistivity. The hardness and the maximum reached load were 7.5 GPa and 13 mN with a scratch depth of about 130 nm, respectively, that is very promising for the structures consisting of two porous AlO x layers with 50% and 85% porosities, correspondingly. Such mechanical properties of coatings can also allow their application as protective layers for other optical coatings.