Structural and reactive evolution of oxidatively grafted Pd catalysts on MnO 2 for the low-temperature oxidation of CO

Isolated Pd atoms supported on high surface area MnO , prepared by the oxidative grafting of (bis(tricyclohexylphosphine-palladium(0)), catalyze (>50 turnovers, 17 h) the low temperature (≤325 K) oxidation of CO (7.7 kPa O , 2.6 kPa CO) with results of / and spectroscopic characterization signify...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (45), p.6861-6864
Main Authors: Hall, Jacklyn N, Kropf, A Jeremy, Kanbur, Uddhav, Dogan, Fulya, Byron, Carly, Wen, Jianguo, Delferro, Massimiliano, Kaphan, David M
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Isolated Pd atoms supported on high surface area MnO , prepared by the oxidative grafting of (bis(tricyclohexylphosphine-palladium(0)), catalyze (>50 turnovers, 17 h) the low temperature (≤325 K) oxidation of CO (7.7 kPa O , 2.6 kPa CO) with results of / and spectroscopic characterization signifying a synergistic role of Pd and MnO in facilitating redox turnovers.
ISSN:1359-7345
1364-548X
DOI:10.1039/D3CC01094E