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Preliminary investigation of an uncertainty budget for uranium isotope ratio analysis using a liquid sampling—atmospheric pressure glow discharge—orbitrap mass spectrometer system
The liquid sampling-atmospheric pressure glow discharge (LS-APGD) ionization source has proven to be an effective analysis tool for making uranium isotope ratio measurements when coupled to high-resolution mass spectrometers, such as the Orbitrap. While previous studies have shown the capabilities o...
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| Published in: | Journal of radioanalytical and nuclear chemistry 2023-07, Vol.332 (7), p.2875-2886 |
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| container_end_page | 2886 |
| container_issue | 7 |
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| container_title | Journal of radioanalytical and nuclear chemistry |
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| creator | Goodwin, Joseph V. Manard, Benjamin T. Ticknor, Brian W. Rogers, Kayron T. Hexel, Cole R. Cable-Dunlap, Paula Marcus, R. Kenneth |
| description | The liquid sampling-atmospheric pressure glow discharge (LS-APGD) ionization source has proven to be an effective analysis tool for making uranium isotope ratio measurements when coupled to high-resolution mass spectrometers, such as the Orbitrap. While previous studies have shown the capabilities of the LS-APGD for isotope ratio determination, a systematic evaluation of the measurement uncertainty of the technique has not been conducted. To this end, the International Standards Organizations (ISO) guidelines to the expression of uncertainty in measurement (GUM analysis) have been applied to generate an uncertainty budget. Presented here, a preliminary assessment derived from the GUM analysis was performed. The uncertainty in the instrument blank determination has been identified as a primary factor contributing to measurement uncertainty for the LS-APGD-Orbitrap method. These findings for the specific test case of uranium isotopic analysis will be invaluable in applications across the breadth of isotope ratio mass spectrometry performed on this unique instrumental platform.
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| doi_str_mv | 10.1007/s10967-023-08901-9 |
| format | article |
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Graphical abstract</description><subject>Atmospheric pressure</subject><subject>Budgets</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diagnostic Radiology</subject><subject>Glow discharges</subject><subject>GUM</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inorganic Chemistry</subject><subject>Investigations</subject><subject>Isotope ratios</subject><subject>Mass spectrometers</subject><subject>Mass spectrometry</subject><subject>Nuclear Chemistry</subject><subject>Nuclear energy</subject><subject>Nuclear Physics</subject><subject>nuclear safeguards</subject><subject>Physical Chemistry</subject><subject>RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY</subject><subject>Sampling</subject><subject>Uncertainty</subject><subject>uncertainty evaluation</subject><subject>Uranium</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kc1u1DAUhSMEEkPhBVhZsE7rn3FiL6sKClKlsoC15XGuM64SO_V1QLPjIXgX3ocnwUOQ2CEvLF1_5-j6nKZ5zeglo7S_QkZ117eUi5YqTVmrnzQ7JpVqea_o02ZXX7pW9oI9b14gPlBKtVJi1_z8lGEKc4g2n0iIXwFLGG0JKZLkiY1kjQ5ysSGWEzmswwiF-JTJmm0M60wCppIWIPmsqbydThiQrBjiSCyZwuMaBoJ2XqY6-fX9hy1zwuUIOTiyZEBcM5BxSt_IENAdbR6hUikfQsl2IbNFJLiAKznNUCATPGGB-WXzzNsJ4dXf-6L58v7d55sP7d397ceb67vWCUVLq5jmvRVaeUftsLea032nJXiQ3cF1Q0-lo9xL54FyKjuhhGedGg7DXu6pc-KiebP5phqMQRcKuKNLMdaNDNOa9YJX6O0GLTk9rjVC85DWXLNAw5VgiirORaUuN2q0E5gQfao_dPUMMIdqCT7U-XUv5Z4JLc-2fBO4nBAzeLPkMNeiDKPmXLvZaje1XPOndqOrSGwirHAcIf_b5T-q34tOt6w</recordid><startdate>20230701</startdate><enddate>20230701</enddate><creator>Goodwin, Joseph V.</creator><creator>Manard, Benjamin T.</creator><creator>Ticknor, Brian W.</creator><creator>Rogers, Kayron T.</creator><creator>Hexel, Cole R.</creator><creator>Cable-Dunlap, Paula</creator><creator>Marcus, R. 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Kenneth</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c380t-81927a398fc0ad4a9204695efe56bc6d705c02f5cfe02056383f168dbd4540cc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Atmospheric pressure</topic><topic>Budgets</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diagnostic Radiology</topic><topic>Glow discharges</topic><topic>GUM</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inorganic Chemistry</topic><topic>Investigations</topic><topic>Isotope ratios</topic><topic>Mass spectrometers</topic><topic>Mass spectrometry</topic><topic>Nuclear Chemistry</topic><topic>Nuclear energy</topic><topic>Nuclear Physics</topic><topic>nuclear safeguards</topic><topic>Physical Chemistry</topic><topic>RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY</topic><topic>Sampling</topic><topic>Uncertainty</topic><topic>uncertainty evaluation</topic><topic>Uranium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Goodwin, Joseph V.</creatorcontrib><creatorcontrib>Manard, Benjamin T.</creatorcontrib><creatorcontrib>Ticknor, Brian W.</creatorcontrib><creatorcontrib>Rogers, Kayron T.</creatorcontrib><creatorcontrib>Hexel, Cole R.</creatorcontrib><creatorcontrib>Cable-Dunlap, Paula</creatorcontrib><creatorcontrib>Marcus, R. 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Kenneth</au><aucorp>Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preliminary investigation of an uncertainty budget for uranium isotope ratio analysis using a liquid sampling—atmospheric pressure glow discharge—orbitrap mass spectrometer system</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2023-07-01</date><risdate>2023</risdate><volume>332</volume><issue>7</issue><spage>2875</spage><epage>2886</epage><pages>2875-2886</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>The liquid sampling-atmospheric pressure glow discharge (LS-APGD) ionization source has proven to be an effective analysis tool for making uranium isotope ratio measurements when coupled to high-resolution mass spectrometers, such as the Orbitrap. 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| identifier | ISSN: 0236-5731 |
| ispartof | Journal of radioanalytical and nuclear chemistry, 2023-07, Vol.332 (7), p.2875-2886 |
| issn | 0236-5731 1588-2780 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1991732 |
| source | Springer Nature |
| subjects | Atmospheric pressure Budgets Chemistry Chemistry and Materials Science Diagnostic Radiology Glow discharges GUM Hadrons Heavy Ions Inorganic Chemistry Investigations Isotope ratios Mass spectrometers Mass spectrometry Nuclear Chemistry Nuclear energy Nuclear Physics nuclear safeguards Physical Chemistry RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY Sampling Uncertainty uncertainty evaluation Uranium |
| title | Preliminary investigation of an uncertainty budget for uranium isotope ratio analysis using a liquid sampling—atmospheric pressure glow discharge—orbitrap mass spectrometer system |
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