Palladium-Catalyzed Carboxylative Coupling of Allylstannanes and Allyl Halides

A three-component carboxylative coupling between allyl halides, allylstannanes, and CO2 to produce allyl esters is catalyzed by Pd and Pt phosphine complexes. Tentative mechanistic pathways for the catalytic reaction are proposed.

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Bibliographic Details
Published in:Organometallics 2000-04, Vol.19 (8), p.1458-1460
Main Authors: Franks, Russell J, Nicholas, Kenneth M
Format: Article
Language:English
Subjects:
CARBON DIOXIDE
CATALYSIS
HALOGENATED ALIPHATIC HYDROCARBONS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
PALLADIUM COMPLEXES
PHOSPHINES
PLATINUM COMPLEXES
STANNATES
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Description
Summary:A three-component carboxylative coupling between allyl halides, allylstannanes, and CO2 to produce allyl esters is catalyzed by Pd and Pt phosphine complexes. Tentative mechanistic pathways for the catalytic reaction are proposed.
ISSN:0276-7333
1520-6041
DOI:10.1021/om0000966