Pilot installation for the thermo-chemical characterisation of solid wastes

• Published in: Waste management (Elmsford) 2007-01, Vol.27 (3), p.367-374
• Main Authors: Marculescu, C., Antonini, G., Badea, A., Apostol, T.
• Format: Article
• Language: English
• Subjects: Applied sciences; CALORIMETRY; CHEMICAL PROPERTIES; Exact sciences and technology; HEAT TREATMENTS; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; KINETICS; Other wastes and particular components of wastes; OXIDATION; Oxidation-Reduction; Pilot Projects; POLLUTANTS; Pollution; PYROLYSIS; Refuse Disposal; SOLID WASTES; Temperature; THERMAL DEGRADATION; THERMAL GRAVIMETRIC ANALYSIS; Time Factors; Urban and domestic wastes; Vibration; Wastes
• ISSN: 0956-053X; 1879-2456
• DOI: 10.1016/j.wasman.2006.02.011

The increasing production and the large variety of wastes require operators of thermal treatment units to continuously adapt the installations or the functioning parameters to the different physical and chemical properties of the wastes. Usually, the treated waste is encountered in the form of heterogeneous mixtures. The classical tests such as thermogravimetry and calorimetric bomb operate component by component, separately. In addition to this, they can analyse only small quantities of waste at a time (a few grams). These common tests are necessary but insufficient in the global waste analysis in the view further thermal treatment. This paper presents an experimental installation, which was designed and built at the CNRS Science Division, Department of Industrial Methods, Compiègne University of Technology, France. It allows the determination of waste thermal and chemical properties by means of thermal treatment. Also, it is capable of continuously analysing significant quantities of waste (up to 50 kg/h) as compared to the classical tests and it can work under various conditions: • oxidant or reductive atmosphere (on choice); • variable temperature between 400 and 1000 °C; • independently set residence time of treated sample in the installation and flow conditions. The installation reproduces the process conditions from incinerators or pyrolysis reactors. It also provides complete information on the kinetics of the waste thermal degradation and on the pollutant emissions. Using different mixtures of components present in the municipal solid waste and also in the reconstituted MSW samples, we defined a series of criteria for characterising waste behaviour during the stages of the main treatment process such as: feeding, devolatilisation/oxidation, advancement, solid residue evacuation, and pollutants emission.