Growth and characterization of Cl-doped ZnO hexagonal nanodisks

• Published in: Journal of solid state chemistry 2011-10, Vol.184 (10), p.2678-2682
• Main Authors: Yousefi, Ramin, Zak, A.K., Mahmoudian, M.R.
• Format: Article
• Language: English
• Subjects: Anionic doping; ANIONS; CHALCOGENIDES; CHARGED PARTICLES; Chemical synthesis methods; Chlorine; Cl-doped ZnO nanodisks; COHERENT SCATTERING; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; DIMENSIONS; Disks; DOPED MATERIALS; EMISSION; EVAPORATION; Exact sciences and technology; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; IONS; LASER SPECTROSCOPY; Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties; LUMINESCENCE; MATERIALS; Materials science; Methods of nanofabrication; Micrometers; Nanocomposites; Nanomaterials; Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals; Nanostructure; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures; OXIDES; OXYGEN COMPOUNDS; PEAKS; PHASE TRANSFORMATIONS; PHOTOLUMINESCENCE; PHOTON EMISSION; Physics; Raman; RAMAN SPECTROSCOPY; SCATTERING; SPECTROSCOPY; STRESSES; Structure of solids and liquids; crystallography; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties); THICKNESS; Undoped ZnO microdisks; X-RAY DIFFRACTION; ZINC COMPOUNDS; Zinc oxide; ZINC OXIDES
• ISSN: 0022-4596; 1095-726X
• DOI: 10.1016/j.jssc.2011.08.001

Cl-doped ZnO nanodisks were grown on a Si(111) substrate using a thermal evaporation method. The prepared nanodisks exhibited a hexagonal shape with an average thickness of 50 nm and average diagonal of 270 nm. In addition, undoped ZnO disks with hexagonal shape were grown under the same conditions, but the sizes of these undoped ZnO disks were on the micrometer order. A possible mechanism was proposed for the growth of the Cl-doped ZnO nanodisks, and it was shown that the Cl 1− anions play a crucial role in controlling the size. X-ray diffraction and Raman spectroscopy clearly showed an extension in the crystal lattice of ZnO because of the presence of chlorine. In addition, these nanodisks produced a strong photoluminescence emission peak in the ultraviolet (UV) region and a weak peak in the green region of the electromagnetic spectrum. Furthermore, the UV peak of the Cl-doped ZnO nanodisks was blueshifted with respect to that of the undoped ZnO disks. Cl-doped ZnO nanodisks and undoped ZnO microdisks have been grown using a thermal evaporation method. [Display omitted] ► Cl-doped ZnO nanodisks with hexagonal shape are grown using a thermal evaporation method. ► It is shown that the Cl 1− anions play a crucial role in controlling the size of the nanodisks. ► XRD and Raman results showed that the Cl-doped ZnO nanodisks structure is under a biaxial stress. ► UV peak of the PL spectrum is blueshifted for the Cl-doped ZnO nanodisks.