Adsorption of volatile organic compounds in porous metal–organic frameworks functionalized by polyoxometalates

The functionalization of porous metal–organic frameworks (Cu 3( BTC) 2) was achieved by incorporating Keggin-type polyoxometalates (POMs), and further optimized via alkali metal ion-exchange. In addition to thermal gravimetric analysis, IR, single-crystal X-ray diffraction, and powder X-ray diffract...

Full description

Saved in:
Bibliographic Details
Published in:Journal of solid state chemistry 2011-11, Vol.184 (11), p.3034-3039
Main Authors: Ma, Feng-Ji, Liu, Shu-Xia, Liang, Da-Dong, Ren, Guo-Jian, Wei, Feng, Chen, Ya-Guang, Su, Zhong-Min
Format: Article
Language:English
Subjects:
ADSORPTION
ALCOHOLS
ALKALI METALS
ALKANES
ALKYLATED AROMATICS
AROMATICS
BENZENE
CATIONS
CHARGED PARTICLES
CHEMICAL ANALYSIS
COHERENT SCATTERING
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
CRYSTALS
CYCLOALKANES
CYCLOHEXANE
DIFFRACTION
ELEMENTS
ENTHALPY
Exact sciences and technology
Functionalization
GRAVIMETRIC ANALYSIS
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
ION EXCHANGE
IONS
MATERIALS
Materials science
MATTER
METALS
MONOCRYSTALS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
Other materials
PHYSICAL PROPERTIES
Physics
Polyoxometalates
POROUS MATERIALS
Porous materials
granular materials
Porous metal–organic frameworks
QUANTITATIVE CHEMICAL ANALYSIS
SCATTERING
Solid surfaces and solid-solid interfaces
SORPTION
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
THERMAL ANALYSIS
THERMAL GRAVIMETRIC ANALYSIS
THERMODYNAMIC PROPERTIES
TOLUENE
VOLATILE MATTER
Volatile organic compounds
VOLATILITY
X-RAY DIFFRACTION
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The functionalization of porous metal–organic frameworks (Cu 3( BTC) 2) was achieved by incorporating Keggin-type polyoxometalates (POMs), and further optimized via alkali metal ion-exchange. In addition to thermal gravimetric analysis, IR, single-crystal X-ray diffraction, and powder X-ray diffraction, the adsorption properties were characterized by N 2 and volatile organic compounds (VOCs) adsorption measurements, including short-chain alcohols ( C
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2011.09.002