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A simple theory of condensation

A simple assumption of the emergence in gas of small atomic clusters consisting of c particles each leads to a phase separation (first-order transition). It reveals itself by the emergence of a “forbidden” density range starting at a certain temperature. Defining this latter value as the critical te...

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Bibliographic Details
Published in:Journal of experimental and theoretical physics 2011-04, Vol.112 (4), p.637-641
Main Author: Rabinovich, S.
Format: Article
Language:English
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Summary:A simple assumption of the emergence in gas of small atomic clusters consisting of c particles each leads to a phase separation (first-order transition). It reveals itself by the emergence of a “forbidden” density range starting at a certain temperature. Defining this latter value as the critical temperature predicts the existence of an interval with the anomalous heat capacity behavior c p ∝ Δ T −1/ c . The value c = 13 suggested in the literature yields the heat capacity exponent α = 0.077.
ISSN:1063-7761
1090-6509
DOI:10.1134/S106377611103006X