Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN2H4)5(H2O)][ZnCl4]

Mixed single crystals of [Co(OCN 2 H 4 ) 5 (H 2 O)][ZnCl 4 ] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction ( R = 0.052 based on 7003 reflections). The crystals consist of [Co(OCN 2 H 4 ) 5 (H 2 O)] 2+ catio...

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Bibliographic Details
Published in:Crystallography reports 2010-03, Vol.55 (2), p.233-236
Main Authors: Furmanova, N. G., Chernaya, T. S., Resnyanskiĭ, V. F., Sulaĭmankulov, K. S.
Format: Article
Language:English
Subjects:
ANIONS
AQUEOUS SOLUTIONS
CATIONS
COBALT
COBALT COMPLEXES
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
CRYSTAL STRUCTURE
Crystallography and Scattering Methods
EVAPORATION
MONOCRYSTALS
Physics
Physics and Astronomy
REFLECTION
Structure of Organic Compounds
UREA
WATER
X-RAY DIFFRACTION
ZINC CHLORIDES
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Summary:Mixed single crystals of [Co(OCN 2 H 4 ) 5 (H 2 O)][ZnCl 4 ] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction ( R = 0.052 based on 7003 reflections). The crystals consist of [Co(OCN 2 H 4 ) 5 (H 2 O)] 2+ cations containing Co atoms in an octahedral coordination and [ZnCl 4 ] 2− ] anions containing Zn atoms in a tetrahedral coordination. The carbamide molecules are involved in both intramolecular and interionic hydrogen bonds. The H 2 O molecule forms hydrogen bonds with the anions.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774510020124