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Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN2H4)5(H2O)][ZnCl4]
Mixed single crystals of [Co(OCN 2 H 4 ) 5 (H 2 O)][ZnCl 4 ] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction ( R = 0.052 based on 7003 reflections). The crystals consist of [Co(OCN 2 H 4 ) 5 (H 2 O)] 2+ catio...
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| Published in: | Crystallography reports 2010-03, Vol.55 (2), p.233-236 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c316t-d7eec95ad4ee1afd249031dd4676d85df12a9a84aa5d2562602d491f26d305903 |
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| cites | cdi_FETCH-LOGICAL-c316t-d7eec95ad4ee1afd249031dd4676d85df12a9a84aa5d2562602d491f26d305903 |
| container_end_page | 236 |
| container_issue | 2 |
| container_start_page | 233 |
| container_title | Crystallography reports |
| container_volume | 55 |
| creator | Furmanova, N. G. Chernaya, T. S. Resnyanskiĭ, V. F. Sulaĭmankulov, K. S. |
| description | Mixed single crystals of [Co(OCN
2
H
4
)
5
(H
2
O)][ZnCl
4
] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction (
R
= 0.052 based on 7003 reflections). The crystals consist of [Co(OCN
2
H
4
)
5
(H
2
O)]
2+
cations containing Co atoms in an octahedral coordination and [ZnCl
4
]
2−
] anions containing Zn atoms in a tetrahedral coordination. The carbamide molecules are involved in both intramolecular and interionic hydrogen bonds. The H
2
O molecule forms hydrogen bonds with the anions. |
| doi_str_mv | 10.1134/S1063774510020124 |
| format | article |
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2
H
4
)
5
(H
2
O)][ZnCl
4
] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction (
R
= 0.052 based on 7003 reflections). The crystals consist of [Co(OCN
2
H
4
)
5
(H
2
O)]
2+
cations containing Co atoms in an octahedral coordination and [ZnCl
4
]
2−
] anions containing Zn atoms in a tetrahedral coordination. The carbamide molecules are involved in both intramolecular and interionic hydrogen bonds. The H
2
O molecule forms hydrogen bonds with the anions.</description><identifier>ISSN: 1063-7745</identifier><identifier>EISSN: 1562-689X</identifier><identifier>DOI: 10.1134/S1063774510020124</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>ANIONS ; AQUEOUS SOLUTIONS ; CATIONS ; COBALT ; COBALT COMPLEXES ; CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY ; CRYSTAL STRUCTURE ; Crystallography and Scattering Methods ; EVAPORATION ; MONOCRYSTALS ; Physics ; Physics and Astronomy ; REFLECTION ; Structure of Organic Compounds ; UREA ; WATER ; X-RAY DIFFRACTION ; ZINC CHLORIDES</subject><ispartof>Crystallography reports, 2010-03, Vol.55 (2), p.233-236</ispartof><rights>Pleiades Publishing, Ltd. 2010</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-d7eec95ad4ee1afd249031dd4676d85df12a9a84aa5d2562602d491f26d305903</citedby><cites>FETCH-LOGICAL-c316t-d7eec95ad4ee1afd249031dd4676d85df12a9a84aa5d2562602d491f26d305903</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27903,27904</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22051224$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Furmanova, N. G.</creatorcontrib><creatorcontrib>Chernaya, T. S.</creatorcontrib><creatorcontrib>Resnyanskiĭ, V. F.</creatorcontrib><creatorcontrib>Sulaĭmankulov, K. S.</creatorcontrib><title>Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN2H4)5(H2O)][ZnCl4]</title><title>Crystallography reports</title><addtitle>Crystallogr. Rep</addtitle><description>Mixed single crystals of [Co(OCN
2
H
4
)
5
(H
2
O)][ZnCl
4
] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction (
R
= 0.052 based on 7003 reflections). The crystals consist of [Co(OCN
2
H
4
)
5
(H
2
O)]
2+
cations containing Co atoms in an octahedral coordination and [ZnCl
4
]
2−
] anions containing Zn atoms in a tetrahedral coordination. The carbamide molecules are involved in both intramolecular and interionic hydrogen bonds. The H
2
O molecule forms hydrogen bonds with the anions.</description><subject>ANIONS</subject><subject>AQUEOUS SOLUTIONS</subject><subject>CATIONS</subject><subject>COBALT</subject><subject>COBALT COMPLEXES</subject><subject>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY</subject><subject>CRYSTAL STRUCTURE</subject><subject>Crystallography and Scattering Methods</subject><subject>EVAPORATION</subject><subject>MONOCRYSTALS</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>REFLECTION</subject><subject>Structure of Organic Compounds</subject><subject>UREA</subject><subject>WATER</subject><subject>X-RAY DIFFRACTION</subject><subject>ZINC CHLORIDES</subject><issn>1063-7745</issn><issn>1562-689X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kF9LwzAUxYMoOKcfwLeAL9tDNTdN0vZRijphuAcVxDFKlqS2o2tGkqHz05sx3wSf7p_zOxfORegSyDVAym6egYg0yxgHQigByo7QALigiciLt-PYRznZ66fozPsVISTPgQ3QunQ7H2SHfXBbFbbOYFvj0Bi8bHvpdljZ9aYzX_utskvZBSx7jb_bXmHVdNa12nj82YYGK-mWch1nPC_taFY-0Qkb89GEzsaL-Xtfdmxxjk5q2Xlz8VuH6PX-7qWcJNPZw2N5O01UCiIkOjNGFVxqZgzIWlNWkBS0ZiITOue6BioLmTMpuaYxpCBUswJqKnRKeGSH6Opw1_rQVl61wahG2b43KlSUEg6UskjBgVLOeu9MXW1cu46hKyDV_qvVn69GDz14fGT7D-Oqld26Pob5x_QDcgF3lw</recordid><startdate>20100301</startdate><enddate>20100301</enddate><creator>Furmanova, N. G.</creator><creator>Chernaya, T. S.</creator><creator>Resnyanskiĭ, V. F.</creator><creator>Sulaĭmankulov, K. S.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20100301</creationdate><title>Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN2H4)5(H2O)][ZnCl4]</title><author>Furmanova, N. G. ; Chernaya, T. S. ; Resnyanskiĭ, V. F. ; Sulaĭmankulov, K. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-d7eec95ad4ee1afd249031dd4676d85df12a9a84aa5d2562602d491f26d305903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>ANIONS</topic><topic>AQUEOUS SOLUTIONS</topic><topic>CATIONS</topic><topic>COBALT</topic><topic>COBALT COMPLEXES</topic><topic>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY</topic><topic>CRYSTAL STRUCTURE</topic><topic>Crystallography and Scattering Methods</topic><topic>EVAPORATION</topic><topic>MONOCRYSTALS</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>REFLECTION</topic><topic>Structure of Organic Compounds</topic><topic>UREA</topic><topic>WATER</topic><topic>X-RAY DIFFRACTION</topic><topic>ZINC CHLORIDES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Furmanova, N. G.</creatorcontrib><creatorcontrib>Chernaya, T. S.</creatorcontrib><creatorcontrib>Resnyanskiĭ, V. F.</creatorcontrib><creatorcontrib>Sulaĭmankulov, K. S.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Crystallography reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Furmanova, N. G.</au><au>Chernaya, T. S.</au><au>Resnyanskiĭ, V. F.</au><au>Sulaĭmankulov, K. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN2H4)5(H2O)][ZnCl4]</atitle><jtitle>Crystallography reports</jtitle><stitle>Crystallogr. Rep</stitle><date>2010-03-01</date><risdate>2010</risdate><volume>55</volume><issue>2</issue><spage>233</spage><epage>236</epage><pages>233-236</pages><issn>1063-7745</issn><eissn>1562-689X</eissn><abstract>Mixed single crystals of [Co(OCN
2
H
4
)
5
(H
2
O)][ZnCl
4
] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction (
R
= 0.052 based on 7003 reflections). The crystals consist of [Co(OCN
2
H
4
)
5
(H
2
O)]
2+
cations containing Co atoms in an octahedral coordination and [ZnCl
4
]
2−
] anions containing Zn atoms in a tetrahedral coordination. The carbamide molecules are involved in both intramolecular and interionic hydrogen bonds. The H
2
O molecule forms hydrogen bonds with the anions.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1063774510020124</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1063-7745 |
| ispartof | Crystallography reports, 2010-03, Vol.55 (2), p.233-236 |
| issn | 1063-7745 1562-689X |
| language | eng |
| recordid | cdi_osti_scitechconnect_22051224 |
| source | Springer Nature |
| subjects | ANIONS AQUEOUS SOLUTIONS CATIONS COBALT COBALT COMPLEXES CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY CRYSTAL STRUCTURE Crystallography and Scattering Methods EVAPORATION MONOCRYSTALS Physics Physics and Astronomy REFLECTION Structure of Organic Compounds UREA WATER X-RAY DIFFRACTION ZINC CHLORIDES |
| title | Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN2H4)5(H2O)][ZnCl4] |
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