Non-Markovian response of ultrafast coherent electronic ring currents in chiral aromatic molecules in a condensed phase

• Published in: The Journal of chemical physics 2013-12, Vol.139 (21), p.214306-214306
• Main Authors: Mineo, H, Lin, S H, Fujimura, Y, Xu, J, Xu, R X, Yan, Y J
• Format: Article
• Language: English
• Subjects: Approximation; CHIRALITY; Coherence; Damping; EQUATIONS; EXCITED STATES; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; INTERACTIONS; Markov chains; MARKOV PROCESS; Mathematical analysis; MATHEMATICAL METHODS AND COMPUTING; MOLECULES; Oxidation; Physics; RING CURRENTS; SEMICLASSICAL APPROXIMATION
• ISSN: 0021-9606; 1089-7690
• DOI: 10.1063/1.4834035

Results of a theoretical study on non-Markov response for femtosecond laser-driven coherent ring currents in chiral aromatic molecules embedded in a condensed phase are presented. Coherent ring currents are generated by coherent excitation of a pair of quasi-degenerated π-electronic excited states. The coherent electronic dynamical behaviors are strongly influenced by interactions between the electronic system and phonon bath in a condensed phase. Here, the bath correlation time is not instantaneous but should be taken to be a finite time in ultrashort time-resolved experiments. In such a case, Markov approximation breaks down. A hierarchical master equation approach for an improved semiclassical Drude dissipation model was adopted to examine the non-Markov effects on ultrafast coherent electronic ring currents of (P)-2,2'-biphenol in a condensed phase. Time evolution of the coherent ring current derived in the hierarchical master equation approach was calculated and compared with those in the Drude model in the Markov approximation and in the static limit. The results show how non-Markovian behaviors in quantum beat signals of ring currents depend on the Drude bath damping constant. Effects of temperatures on ultrafast coherent electronic ring currents are also clarified.