Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-diene dithiocyanate with nickel (II) acetate

The complexation of nickel acetate with tetraaza involves deprotonation of protonated amine nitrogen to form neutral ligand coordinated to the nickel via the four nitrogen atom. The dication complex is paired with thiocyanate anions. The complex was characterized by elemental analysis, UV-VIS and FT...

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Bibliographic Details
Main Authors: Ishak Nur Iliyani Mohd, Yamin, Bohari M
Format: Conference Proceeding
Language:English
Subjects:
ACETATES
ANIONS
Complexation
CRYSTAL STRUCTURE
Crystallography
FOURIER TRANSFORMATION
Fourier transforms
INFRARED SPECTRA
LIGANDS
MATERIALS SCIENCE
NICKEL
NICKEL COMPLEXES
NITROGEN
THIOCYANATES
X RADIATION
X ray spectra
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Summary:The complexation of nickel acetate with tetraaza involves deprotonation of protonated amine nitrogen to form neutral ligand coordinated to the nickel via the four nitrogen atom. The dication complex is paired with thiocyanate anions. The complex was characterized by elemental analysis, UV-VIS and FTIR spectroscopic method. The crystal structure of nickel complex characterized by X-Ray crystallography and adopts square planar geometry.
ISSN:0094-243X
1551-7616
DOI:10.1063/1.4858771