Clathrate formation in the systems Sr–Cu–Ge and {Ba,Sr}–Cu–Ge

In the ternary system Sr–Cu–Ge, a novel clathrate type-I phase was detected, Sr8CuxGe46−x (5.2≤x

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Bibliographic Details
Published in:Journal of solid state chemistry 2014-09, Vol.217, p.169-179
Main Authors: Zeiringer, I., Moser, R., Kneidinger, F., Podloucky, R., Royanian, E., Grytsiv, A., Bauer, E., Giester, G., Falmbigl, M., Rogl, P.
Format: Article
Language:English
Subjects:
ALLOYS
Clathrate type-I
CLATHRATES
COMPARATIVE EVALUATIONS
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Crystal structure
CUBIC LATTICES
DEBYE TEMPERATURE
DENSITY
DENSITY OF STATES
DISPERSION RELATIONS
Dispersions
ELECTRIC CONDUCTIVITY
ELECTRICAL CONDUCTIVITY
Electrical resistivity
Exact sciences and technology
Germanium
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
LATTICE PARAMETERS
Materials science
MONOCRYSTALS
PHASE DIAGRAMS
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Phase diagrams of metals and alloys
Phase equilibria
Physics
Single crystal
Single crystals
SOLID SOLUTIONS
SPACE GROUPS
SPECIFIC HEAT
SPECTRA
Strontium
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
TEMPERATURE DEPENDENCE
THERMAL EXPANSION
THERMAL EXPANSION COEFFICIENT
Thermal expansion
thermomechanical effects and density
Thermal properties of condensed matter
Thermal properties of crystalline solids
X-RAY DIFFRACTION
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Description
Summary:In the ternary system Sr–Cu–Ge, a novel clathrate type-I phase was detected, Sr8CuxGe46−x (5.2≤x
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2014.05.014