Structure and thermal behavior of a nickel complex based on a V-shaped bis(4-(1H-imidazol-1-yl)phenyl)amine ligand

A new coordination polymer {[Ni(BIPA)( bpdc )(H 2 O) 2 ]} n has been prepared based on a new V-shaped bis(4-(1 H -imidazol-1-yl)phenyl)amine (BIPA) ligand. Complex was characterized by elemental analysis, IR spectra, X-ray powder diffraction, thermal analysis and single crystal X-ray analysis. Compl...

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Bibliographic Details
Published in:Crystallography reports 2015-12, Vol.60 (7), p.1013-1018
Main Authors: Jiao, Yan, Wang, Zhe, Qiu, Yu, He, Jing-Man, Chen, Min-dong
Format: Article
Language:English
Subjects:
AMINES
CHEMICAL BONDS
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Crystallography and Scattering Methods
IMIDAZOLES
INFRARED SPECTRA
LIGANDS
MONOCRYSTALS
MULTI-ELEMENT ANALYSIS
NICKEL COMPLEXES
ORGANIC POLYMERS
PHASE STABILITY
PHASE STUDIES
Physics
Physics and Astronomy
Structure of Organic Compounds
THERMAL ANALYSIS
X-RAY DIFFRACTION
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Summary:A new coordination polymer {[Ni(BIPA)( bpdc )(H 2 O) 2 ]} n has been prepared based on a new V-shaped bis(4-(1 H -imidazol-1-yl)phenyl)amine (BIPA) ligand. Complex was characterized by elemental analysis, IR spectra, X-ray powder diffraction, thermal analysis and single crystal X-ray analysis. Complex exhibits a 1D → 3D structure. Hydrogen bonds play an important role in the formation of supramolecular network structure. Thermal analysis indicates that complex exhibits a high thermal stability.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774515070317