Nano/ultrafine grained austenitic stainless steel through the formation and reversion of deformation-induced martensite: Mechanisms, microstructures, mechanical properties, and TRIP effect

• Published in: Materials characterization 2015-05, Vol.103, p.150-161
• Main Authors: Shirdel, M., Mirzadeh, H., Parsa, M.H.
• Format: Article
• Language: English
• Subjects: ANNEALING; AUSTENITE; Austenitic stainless steels; CARBIDES; DEFORMATION; GRAIN GROWTH; GRAIN REFINEMENT; GRAIN SIZE; MAGNETIZATION; MARTENSITE; Martensitic transformations; MATERIALS SCIENCE; Microstructure; NANOSTRUCTURES; Phase reversion-induced grain refinement; PHASE TRANSFORMATIONS; PLASTICITY; PRECIPITATION; REDUCTION; Reversion; Reversion mechanism; ROLLING; SATURATION; STAINLESS STEEL-304L; STRAIN HARDENING; Thermodynamics; Thermomechanical processing; TRIP-aided steel; Ultrafine-grained materials; X-RAY DIFFRACTION
• ISSN: 1044-5803; 1873-4189
• DOI: 10.1016/j.matchar.2015.03.031

A comprehensive study was carried out on the strain-induced martensitic transformation, its reversion to austenite, the resultant grain refinement, and the enhancement of strength and strain-hardening ability through the transformation-induced plasticity (TRIP) effect in a commercial austenitic 304L stainless steel with emphasis on the mechanisms and the microstructural evolution. A straightforward magnetic measurement device, which is based on the measurement of the saturation magnetization, for evaluating the amount of strain-induced martensite after cold rolling and reversion annealing in metastable austenitic stainless steels was used, which its results were in good consistency with those of the X-ray diffraction (XRD) method. A new parameter called the effective reduction in thickness was introduced, which corresponds to the reasonable upper bound on the obtainable martensite fraction based on the saturation in the martensitic transformation. By means of thermodynamics calculations, the reversion mechanisms were estimated and subsequently validated by experimental results. The signs of thermal martensitic transformation at cooling stage after reversion at 850°C were found, which was attributed to the rise in the martensite start temperature due to the carbide precipitation. After the reversion treatment, the average grain sizes were around 500nm and the nanometric grains of the size of ~65nm were also detected. The intense grain refinement led to the enhanced mechanical properties and observation of the change in the work-hardening capacity and TRIP effect behavior. A practical map as a guidance for grain refining and characterizing the stability against grain growth was proposed, which shows the limitation of the reversion mechanism for refinement of grain size. [Display omitted] •Nano/ultrafine grained austenitic stainless steel through martensite treatment•A parameter descriptive of a reasonable upper bound on the obtainable martensite•Characterization of martensite by virtue of a new developed magnetic device•Investigation of mechanical properties and TRIP effect and the effect of grain size