Interfacial enhancement of polypropylene composites modified with sorbitol derivatives and siloxane-silsesquioxane resin

Composites based on polypropylene (iPP) modified with a sorbitol derivative (NX8000) and siloxane-silsesquioxane resin (SiOPh) containing maleated polypropylene (MAPP) as compatibilizer were prepared by melt extrusion. Calorimetric investigations were carried out using differential scanning calorime...

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Main Authors: Dobrzyńska-Mizera, Monika, Sterzyński, Tomasz, Dutkiewicz, Michał, Di Lorenzo, Maria Laura
Format: Conference Proceeding
Language:English
Subjects:
ADHESION
CALORIMETRY
Compatibility
Composite materials
CRYSTALLIZATION
Differential scanning calorimetry
EXTRUSION
FILLERS
Heat measurement
KINETICS
MATERIALS SCIENCE
Mechanical properties
Plastic properties
PLASTICITY
Polymer matrix composites
POLYPROPYLENE
SCANNING ELECTRON MICROSCOPY
SORBITOL
Tensile tests
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creator Dobrzyńska-Mizera, Monika
Sterzyński, Tomasz
Dutkiewicz, Michał
Di Lorenzo, Maria Laura
description Composites based on polypropylene (iPP) modified with a sorbitol derivative (NX8000) and siloxane-silsesquioxane resin (SiOPh) containing maleated polypropylene (MAPP) as compatibilizer were prepared by melt extrusion. Calorimetric investigations were carried out using differential scanning calorimetry (DSC), whereas the morphological and mechanical properties were investigated by scanning electron microscopy (SEM) and static tensile tests. DSC measurements revealed no influence of SiOPh and a slight effect of MAPP addition on the crystallization kinetics of polypropylene. Additionally, the introduction of MAPP into the iPP+NX8000+SiOPh composites increased plastic properties of the samples. All the above was attributed to the compatibilizing effect of MAPP which improved interfacial adhesion between iPP, NX8000 and SiOPh. This phenomenon was also confirmed by the SEM images illustrating more homogenous distribution of the filler in the compatibilized samples.
doi_str_mv 10.1063/1.4937327
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source American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)
subjects ADHESION
CALORIMETRY
Compatibility
Composite materials
CRYSTALLIZATION
Differential scanning calorimetry
EXTRUSION
FILLERS
Heat measurement
KINETICS
MATERIALS SCIENCE
Mechanical properties
Plastic properties
PLASTICITY
Polymer matrix composites
POLYPROPYLENE
SCANNING ELECTRON MICROSCOPY
SORBITOL
Tensile tests
title Interfacial enhancement of polypropylene composites modified with sorbitol derivatives and siloxane-silsesquioxane resin
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