Characterisation of magnesium silicate hydrate phases (M-S-H): A combined approach using synchrotron-based absorption-spectroscopy and ab initio calculations

• Published in: Cement and concrete research 2018-07, Vol.109, p.175-183
• Main Authors: Vespa, M., Lothenbach, B., Dähn, R., Huthwelker, T., Wieland, E.
• Format: Article
• Language: English
• Subjects: ABSORPTION SPECTROSCOPY; Adsorption; Atomic structure; Brucite; Calcium silicate hydrate; CALCIUM SILICATES; Cement; CEMENTS; DEFECTS; HYDRATES; HYDROXYL RADICALS; Interlayers; M-S-H; MAGNESIUM; Magnesium hydroxide; MAGNESIUM SILICATES; MATERIALS SCIENCE; Mathematical analysis; MIXING; Phases; ROCKS; SILICA; SILICON; Silicon dioxide; Synchrotron-based XAS; TALC; X-RAY SPECTROSCOPY
• ISSN: 0008-8846; 1873-3948
• DOI: 10.1016/j.cemconres.2018.03.011

The formation of magnesium-silicate-hydrate (M-S-H) phases has been observed at the interface between cement and argillaceous rock formations. In this study the atomic structure of M-S-H and magnesium‑calcium-silicate-hydrate (M-C-S-H, a mixing with Ca) was performed by Mg K-edge X-ray absorption spectroscopy combined with ab-initio calculations. The results show that all magnesium containing phases have a TOT phyllosilicate structure with silica defects creating end of silica chains and an interlayer composed of Mg bound to hydroxide groups. Significant differences are observable between the M-S-H and the M-C-S-H. Firstly, the M-C-S-H phases have an enlarged structure compared to the M-S-H phases. Secondly, the results indicate that at least two geometrically distinct Mg octahedral sites are present for all phases. It is concluded that the Mg octahedra are attached to both Si tetrahedra in a manner similarly to that in talc and, to hydroxide groups in a manner similar to that in brucite.