Loading…
Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range
Novel amorphous perfluorinated polymers are synthesized and characterized using terahertz (THz) and x-ray spectra. The polymerization of such polymers in which all H atoms are replaced by F is examined. Their optical properties in the THz range show a record low index of refraction for solids in thi...
Saved in:
| Published in: | Journal of applied spectroscopy 2018-07, Vol.85 (3), p.374-380 |
|---|---|
| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c417t-2ebc4fde15846016c7b54a51d130cd16a1617f52768abbea294738792990ca603 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c417t-2ebc4fde15846016c7b54a51d130cd16a1617f52768abbea294738792990ca603 |
| container_end_page | 380 |
| container_issue | 3 |
| container_start_page | 374 |
| container_title | Journal of applied spectroscopy |
| container_volume | 85 |
| creator | Kitai, M. S. Volkov, W. W. Zharov, A. A. Zubavichus, Ya. V. Konarev, P. V. Nazarov, M. M. Polunin, E. V. Pogodina, Yu. E. Sokolov, V. I. |
| description | Novel amorphous perfluorinated polymers are synthesized and characterized using terahertz (THz) and x-ray spectra. The polymerization of such polymers in which all H atoms are replaced by F is examined. Their optical properties in the THz range show a record low index of refraction for solids in this range. The minimal possible index of refraction for such polymers is estimated. These materials are demonstrated to be highly transparent. The position of a weak absorption maximum in the range 1–2 THz is compared with the characteristic distance between the polymer structural elements that is obtained from an x-ray diffraction analysis of these materials. |
| doi_str_mv | 10.1007/s10812-018-0660-2 |
| format | article |
| fullrecord | <record><control><sourceid>gale_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_22809983</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A550613884</galeid><sourcerecordid>A550613884</sourcerecordid><originalsourceid>FETCH-LOGICAL-c417t-2ebc4fde15846016c7b54a51d130cd16a1617f52768abbea294738792990ca603</originalsourceid><addsrcrecordid>eNp1kU1r3DAQhkVpodu0P6A3QU89OJ2RbUk-LqEfgdAsaXoWWnm8q-C1XEmGpr--WlwIOZQ5DAzPMwzzMvYe4RIB1KeEoFFUgLoCKaESL9gGW1VXWjbqJdsACKw6qNVr9ialBwDotIAN-347Z-_syHcxzBSzp8TDwLenEOdjWBLfURzGJUQ_2Uw934Xx8UQxcT_xfCR-T9Eei_eH39npQG_Zq8GOid796xfs55fP91ffqpvbr9dX25vKNahyJWjvmqEnbHUjAaVT-7axLfZYg-tRWpSohlYoqe1-T1Z0jaq16kTXgbMS6gv2Yd0bUvYmOZ_JHV2YJnLZCKGh63T9RM0x_FooZfMQljiVw4wo75KixrYp1OVKHexIxk9DyNG6Uj2dfNlJgy_zbduCxFrrs_DxmVCYTL_zwS4pmesfd89ZXFkXQ0qRBjNHf7Lx0SCYc3JmTc6U5Mw5OSOKI1YnFbY8NT6d_X_pL5_vmJg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2081623154</pqid></control><display><type>article</type><title>Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range</title><source>Springer Nature</source><creator>Kitai, M. S. ; Volkov, W. W. ; Zharov, A. A. ; Zubavichus, Ya. V. ; Konarev, P. V. ; Nazarov, M. M. ; Polunin, E. V. ; Pogodina, Yu. E. ; Sokolov, V. I.</creator><creatorcontrib>Kitai, M. S. ; Volkov, W. W. ; Zharov, A. A. ; Zubavichus, Ya. V. ; Konarev, P. V. ; Nazarov, M. M. ; Polunin, E. V. ; Pogodina, Yu. E. ; Sokolov, V. I.</creatorcontrib><description>Novel amorphous perfluorinated polymers are synthesized and characterized using terahertz (THz) and x-ray spectra. The polymerization of such polymers in which all H atoms are replaced by F is examined. Their optical properties in the THz range show a record low index of refraction for solids in this range. The minimal possible index of refraction for such polymers is estimated. These materials are demonstrated to be highly transparent. The position of a weak absorption maximum in the range 1–2 THz is compared with the characteristic distance between the polymer structural elements that is obtained from an x-ray diffraction analysis of these materials.</description><identifier>ISSN: 0021-9037</identifier><identifier>EISSN: 1573-8647</identifier><identifier>DOI: 10.1007/s10812-018-0660-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>ABSORPTION ; Analytical Chemistry ; Atomic/Molecular Structure and Spectra ; Chemical synthesis ; Comparative analysis ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Optical properties ; Physics ; Physics and Astronomy ; POLYMERIZATION ; Polymers ; Refraction ; REFRACTIVE INDEX ; Refractivity ; Structural members ; THZ RANGE ; X ray spectra ; X-RAY DIFFRACTION</subject><ispartof>Journal of applied spectroscopy, 2018-07, Vol.85 (3), p.374-380</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c417t-2ebc4fde15846016c7b54a51d130cd16a1617f52768abbea294738792990ca603</citedby><cites>FETCH-LOGICAL-c417t-2ebc4fde15846016c7b54a51d130cd16a1617f52768abbea294738792990ca603</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22809983$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Kitai, M. S.</creatorcontrib><creatorcontrib>Volkov, W. W.</creatorcontrib><creatorcontrib>Zharov, A. A.</creatorcontrib><creatorcontrib>Zubavichus, Ya. V.</creatorcontrib><creatorcontrib>Konarev, P. V.</creatorcontrib><creatorcontrib>Nazarov, M. M.</creatorcontrib><creatorcontrib>Polunin, E. V.</creatorcontrib><creatorcontrib>Pogodina, Yu. E.</creatorcontrib><creatorcontrib>Sokolov, V. I.</creatorcontrib><title>Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range</title><title>Journal of applied spectroscopy</title><addtitle>J Appl Spectrosc</addtitle><description>Novel amorphous perfluorinated polymers are synthesized and characterized using terahertz (THz) and x-ray spectra. The polymerization of such polymers in which all H atoms are replaced by F is examined. Their optical properties in the THz range show a record low index of refraction for solids in this range. The minimal possible index of refraction for such polymers is estimated. These materials are demonstrated to be highly transparent. The position of a weak absorption maximum in the range 1–2 THz is compared with the characteristic distance between the polymer structural elements that is obtained from an x-ray diffraction analysis of these materials.</description><subject>ABSORPTION</subject><subject>Analytical Chemistry</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemical synthesis</subject><subject>Comparative analysis</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Optical properties</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>POLYMERIZATION</subject><subject>Polymers</subject><subject>Refraction</subject><subject>REFRACTIVE INDEX</subject><subject>Refractivity</subject><subject>Structural members</subject><subject>THZ RANGE</subject><subject>X ray spectra</subject><subject>X-RAY DIFFRACTION</subject><issn>0021-9037</issn><issn>1573-8647</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kU1r3DAQhkVpodu0P6A3QU89OJ2RbUk-LqEfgdAsaXoWWnm8q-C1XEmGpr--WlwIOZQ5DAzPMwzzMvYe4RIB1KeEoFFUgLoCKaESL9gGW1VXWjbqJdsACKw6qNVr9ialBwDotIAN-347Z-_syHcxzBSzp8TDwLenEOdjWBLfURzGJUQ_2Uw934Xx8UQxcT_xfCR-T9Eei_eH39npQG_Zq8GOid796xfs55fP91ffqpvbr9dX25vKNahyJWjvmqEnbHUjAaVT-7axLfZYg-tRWpSohlYoqe1-T1Z0jaq16kTXgbMS6gv2Yd0bUvYmOZ_JHV2YJnLZCKGh63T9RM0x_FooZfMQljiVw4wo75KixrYp1OVKHexIxk9DyNG6Uj2dfNlJgy_zbduCxFrrs_DxmVCYTL_zwS4pmesfd89ZXFkXQ0qRBjNHf7Lx0SCYc3JmTc6U5Mw5OSOKI1YnFbY8NT6d_X_pL5_vmJg</recordid><startdate>20180701</startdate><enddate>20180701</enddate><creator>Kitai, M. S.</creator><creator>Volkov, W. W.</creator><creator>Zharov, A. A.</creator><creator>Zubavichus, Ya. V.</creator><creator>Konarev, P. V.</creator><creator>Nazarov, M. M.</creator><creator>Polunin, E. V.</creator><creator>Pogodina, Yu. E.</creator><creator>Sokolov, V. I.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>OTOTI</scope></search><sort><creationdate>20180701</creationdate><title>Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range</title><author>Kitai, M. S. ; Volkov, W. W. ; Zharov, A. A. ; Zubavichus, Ya. V. ; Konarev, P. V. ; Nazarov, M. M. ; Polunin, E. V. ; Pogodina, Yu. E. ; Sokolov, V. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c417t-2ebc4fde15846016c7b54a51d130cd16a1617f52768abbea294738792990ca603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>ABSORPTION</topic><topic>Analytical Chemistry</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemical synthesis</topic><topic>Comparative analysis</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Optical properties</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>POLYMERIZATION</topic><topic>Polymers</topic><topic>Refraction</topic><topic>REFRACTIVE INDEX</topic><topic>Refractivity</topic><topic>Structural members</topic><topic>THZ RANGE</topic><topic>X ray spectra</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kitai, M. S.</creatorcontrib><creatorcontrib>Volkov, W. W.</creatorcontrib><creatorcontrib>Zharov, A. A.</creatorcontrib><creatorcontrib>Zubavichus, Ya. V.</creatorcontrib><creatorcontrib>Konarev, P. V.</creatorcontrib><creatorcontrib>Nazarov, M. M.</creatorcontrib><creatorcontrib>Polunin, E. V.</creatorcontrib><creatorcontrib>Pogodina, Yu. E.</creatorcontrib><creatorcontrib>Sokolov, V. I.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kitai, M. S.</au><au>Volkov, W. W.</au><au>Zharov, A. A.</au><au>Zubavichus, Ya. V.</au><au>Konarev, P. V.</au><au>Nazarov, M. M.</au><au>Polunin, E. V.</au><au>Pogodina, Yu. E.</au><au>Sokolov, V. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range</atitle><jtitle>Journal of applied spectroscopy</jtitle><stitle>J Appl Spectrosc</stitle><date>2018-07-01</date><risdate>2018</risdate><volume>85</volume><issue>3</issue><spage>374</spage><epage>380</epage><pages>374-380</pages><issn>0021-9037</issn><eissn>1573-8647</eissn><abstract>Novel amorphous perfluorinated polymers are synthesized and characterized using terahertz (THz) and x-ray spectra. The polymerization of such polymers in which all H atoms are replaced by F is examined. Their optical properties in the THz range show a record low index of refraction for solids in this range. The minimal possible index of refraction for such polymers is estimated. These materials are demonstrated to be highly transparent. The position of a weak absorption maximum in the range 1–2 THz is compared with the characteristic distance between the polymer structural elements that is obtained from an x-ray diffraction analysis of these materials.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10812-018-0660-2</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9037 |
| ispartof | Journal of applied spectroscopy, 2018-07, Vol.85 (3), p.374-380 |
| issn | 0021-9037 1573-8647 |
| language | eng |
| recordid | cdi_osti_scitechconnect_22809983 |
| source | Springer Nature |
| subjects | ABSORPTION Analytical Chemistry Atomic/Molecular Structure and Spectra Chemical synthesis Comparative analysis INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Optical properties Physics Physics and Astronomy POLYMERIZATION Polymers Refraction REFRACTIVE INDEX Refractivity Structural members THZ RANGE X ray spectra X-RAY DIFFRACTION |
| title | Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T19%3A33%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Optical%20Properties%20of%20Amorphous%20Perfluorinated%20Polymers%20in%20the%20Terahertz%20Range&rft.jtitle=Journal%20of%20applied%20spectroscopy&rft.au=Kitai,%20M.%20S.&rft.date=2018-07-01&rft.volume=85&rft.issue=3&rft.spage=374&rft.epage=380&rft.pages=374-380&rft.issn=0021-9037&rft.eissn=1573-8647&rft_id=info:doi/10.1007/s10812-018-0660-2&rft_dat=%3Cgale_osti_%3EA550613884%3C/gale_osti_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c417t-2ebc4fde15846016c7b54a51d130cd16a1617f52768abbea294738792990ca603%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2081623154&rft_id=info:pmid/&rft_galeid=A550613884&rfr_iscdi=true |