Cu Based Dilute Alloys for Tuning the C2+ Selectivity of Electrochemical CO2 Reduction

Abstract Electrochemical CO 2 reduction is a promising technology for replacing fossil fuel feedstocks in the chemical industry but further improvements in catalyst selectivity need to be made. So far, only copper‐based catalysts have shown efficient conversion of CO 2 into the desired multi‐carbon...

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Bibliographic Details
Published in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2024-07, Vol.N/A (N/A)
Main Authors: Crandall, Bradie S., Qi, Zhen, Foucher, Alexandre C., Weitzner, Stephen E., Akhade, Sneha A., Liu, Xin, Kashi, Ajay R., Buckley, Aya K., Ma, Sichao, Stach, Eric A., Varley, Joel B., Jiao, Feng, Biener, Juergen
Format: Article
Language:English
Subjects:
alloy
catalyst morphology
copper catalyst
density functional theory
electrochemical CO2 reduction
energy efficiency
MATERIALS SCIENCE
physical vapor deposition
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Summary:Abstract Electrochemical CO 2 reduction is a promising technology for replacing fossil fuel feedstocks in the chemical industry but further improvements in catalyst selectivity need to be made. So far, only copper‐based catalysts have shown efficient conversion of CO 2 into the desired multi‐carbon (C 2+ ) products. This work explores Cu‐based dilute alloys to systematically tune the energy landscape of CO 2 electrolysis toward C 2+ products. Selection of the dilute alloy components is guided by grand canonical density functional theory simulations using the calculated binding energies of the reaction intermediates CO*, CHO*, and OCCO* dimer as descriptors for the selectivity toward C 2+ products. A physical vapor deposition catalyst testing platform is employed to isolate the effect of alloy composition on the C 2+ /C 1 product branching ratio without interference from catalyst morphology or catalyst integration. Six dilute alloy catalysts are prepared and tested with respect to their C 2+ /C 1 product ratio using different electrolyzer environments including selected tests in a 100‐cm 2 electrolyzer. Consistent with theory, CuAl, CuB, CuGa and especially CuSc show increased selectivity toward C 2+ products by making CO dimerization energetically more favorable on the dominant Cu facets, demonstrating the power of using the dilute alloy approach to tune the selectivity of CO 2 electrolysis.
ISSN:1613-6810