Loading…
Mesoscopic correlation of supramolecular chirality in one-dimensional hydrogen-bonded assemblies
The ordering of 4-[trans-2-(pyrid-4-yl-vinyl)] benzoic acid, a two-dimensional chiral species, was studied by scanning tunneling microscopy at noble metal surfaces. Homochiral molecules self-assemble in supramolecular chiral hydrogen-bonded twin chains, which order in nanogratings where the supramol...
Saved in:
Published in: | Physical review letters 2001-08, Vol.87 (9), p.096101-096101, Article 096101 |
---|---|
Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c385t-eaaa4a5eb635e5d6e4622c959f9712aa0a3b52781b909c6930a9276828b5562d3 |
---|---|
cites | cdi_FETCH-LOGICAL-c385t-eaaa4a5eb635e5d6e4622c959f9712aa0a3b52781b909c6930a9276828b5562d3 |
container_end_page | 096101 |
container_issue | 9 |
container_start_page | 096101 |
container_title | Physical review letters |
container_volume | 87 |
creator | Weckesser, J De Vita, A Barth, J V Cai, C Kern, K |
description | The ordering of 4-[trans-2-(pyrid-4-yl-vinyl)] benzoic acid, a two-dimensional chiral species, was studied by scanning tunneling microscopy at noble metal surfaces. Homochiral molecules self-assemble in supramolecular chiral hydrogen-bonded twin chains, which order in nanogratings where the supramolecular chirality is strictly correlated over the entire microm domains without intimate molecular contact. Model simulations indicate that the underlying mesoscopic chiral resolution is associated with twin chains acting as chiroselective templates for transient molecular attachment, which process mediates the gratings' evolution. |
doi_str_mv | 10.1103/PhysRevLett.87.096101 |
format | article |
fullrecord | <record><control><sourceid>proquest_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_40277473</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>71143222</sourcerecordid><originalsourceid>FETCH-LOGICAL-c385t-eaaa4a5eb635e5d6e4622c959f9712aa0a3b52781b909c6930a9276828b5562d3</originalsourceid><addsrcrecordid>eNpNkU1r3DAQhkVoabZJf0KCoZCbt_qwLOtYQpsWtjSE5KyO5dmuimxtNHJg_30ddqE9zWGedwbeh7ErwddCcPXpfnegB3zZYCnrzqy5bQUXZ2wluLG1EaJ5w1acK1Fbzs05e0_0h3MuZNu9Y-dCaCW06Vbs1w-kRD7tg698yhkjlJCmKm0rmvcZxhTRzxFy5XchQwzlUIVlPWE9hBEnWmCI1e4w5PQbp7pP04BDBUQ49jEgXbK3W4iEH07zgj19_fJ4-63e_Lz7fvt5U3vV6VIjADSgsW-VRj202LRSeqvt1hohATioXkvTid5y61urOFhp2k52vdatHNQF-3i8m6gERz4U9Dufpgl9cQ2XxjRGLdTNkdrn9DwjFTcG8hgjTJhmcq_FKSnlAuoj6HMiyrh1-xxGyAcnuHsV4P4T4DrjjgKW3PXpwdyPOPxLnRpXfwFaJIXI</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>71143222</pqid></control><display><type>article</type><title>Mesoscopic correlation of supramolecular chirality in one-dimensional hydrogen-bonded assemblies</title><source>American Physical Society:Jisc Collections:APS Read and Publish 2023-2025 (reading list)</source><creator>Weckesser, J ; De Vita, A ; Barth, J V ; Cai, C ; Kern, K</creator><creatorcontrib>Weckesser, J ; De Vita, A ; Barth, J V ; Cai, C ; Kern, K</creatorcontrib><description>The ordering of 4-[trans-2-(pyrid-4-yl-vinyl)] benzoic acid, a two-dimensional chiral species, was studied by scanning tunneling microscopy at noble metal surfaces. Homochiral molecules self-assemble in supramolecular chiral hydrogen-bonded twin chains, which order in nanogratings where the supramolecular chirality is strictly correlated over the entire microm domains without intimate molecular contact. Model simulations indicate that the underlying mesoscopic chiral resolution is associated with twin chains acting as chiroselective templates for transient molecular attachment, which process mediates the gratings' evolution.</description><identifier>ISSN: 0031-9007</identifier><identifier>EISSN: 1079-7114</identifier><identifier>DOI: 10.1103/PhysRevLett.87.096101</identifier><identifier>PMID: 11531578</identifier><language>eng</language><publisher>United States: The American Physical Society</publisher><subject>BENZOIC ACID ; CHAINS ; CHIRALITY ; ENANTIOMORPHS ; PHYSICS OF ELEMENTARY PARTICLES AND FIELDS ; RESOLUTION ; SCANNING TUNNELING MICROSCOPY ; TRANSIENTS</subject><ispartof>Physical review letters, 2001-08, Vol.87 (9), p.096101-096101, Article 096101</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-eaaa4a5eb635e5d6e4622c959f9712aa0a3b52781b909c6930a9276828b5562d3</citedby><cites>FETCH-LOGICAL-c385t-eaaa4a5eb635e5d6e4622c959f9712aa0a3b52781b909c6930a9276828b5562d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11531578$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/40277473$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Weckesser, J</creatorcontrib><creatorcontrib>De Vita, A</creatorcontrib><creatorcontrib>Barth, J V</creatorcontrib><creatorcontrib>Cai, C</creatorcontrib><creatorcontrib>Kern, K</creatorcontrib><title>Mesoscopic correlation of supramolecular chirality in one-dimensional hydrogen-bonded assemblies</title><title>Physical review letters</title><addtitle>Phys Rev Lett</addtitle><description>The ordering of 4-[trans-2-(pyrid-4-yl-vinyl)] benzoic acid, a two-dimensional chiral species, was studied by scanning tunneling microscopy at noble metal surfaces. Homochiral molecules self-assemble in supramolecular chiral hydrogen-bonded twin chains, which order in nanogratings where the supramolecular chirality is strictly correlated over the entire microm domains without intimate molecular contact. Model simulations indicate that the underlying mesoscopic chiral resolution is associated with twin chains acting as chiroselective templates for transient molecular attachment, which process mediates the gratings' evolution.</description><subject>BENZOIC ACID</subject><subject>CHAINS</subject><subject>CHIRALITY</subject><subject>ENANTIOMORPHS</subject><subject>PHYSICS OF ELEMENTARY PARTICLES AND FIELDS</subject><subject>RESOLUTION</subject><subject>SCANNING TUNNELING MICROSCOPY</subject><subject>TRANSIENTS</subject><issn>0031-9007</issn><issn>1079-7114</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNpNkU1r3DAQhkVoabZJf0KCoZCbt_qwLOtYQpsWtjSE5KyO5dmuimxtNHJg_30ddqE9zWGedwbeh7ErwddCcPXpfnegB3zZYCnrzqy5bQUXZ2wluLG1EaJ5w1acK1Fbzs05e0_0h3MuZNu9Y-dCaCW06Vbs1w-kRD7tg698yhkjlJCmKm0rmvcZxhTRzxFy5XchQwzlUIVlPWE9hBEnWmCI1e4w5PQbp7pP04BDBUQ49jEgXbK3W4iEH07zgj19_fJ4-63e_Lz7fvt5U3vV6VIjADSgsW-VRj202LRSeqvt1hohATioXkvTid5y61urOFhp2k52vdatHNQF-3i8m6gERz4U9Dufpgl9cQ2XxjRGLdTNkdrn9DwjFTcG8hgjTJhmcq_FKSnlAuoj6HMiyrh1-xxGyAcnuHsV4P4T4DrjjgKW3PXpwdyPOPxLnRpXfwFaJIXI</recordid><startdate>20010827</startdate><enddate>20010827</enddate><creator>Weckesser, J</creator><creator>De Vita, A</creator><creator>Barth, J V</creator><creator>Cai, C</creator><creator>Kern, K</creator><general>The American Physical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>20010827</creationdate><title>Mesoscopic correlation of supramolecular chirality in one-dimensional hydrogen-bonded assemblies</title><author>Weckesser, J ; De Vita, A ; Barth, J V ; Cai, C ; Kern, K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-eaaa4a5eb635e5d6e4622c959f9712aa0a3b52781b909c6930a9276828b5562d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>BENZOIC ACID</topic><topic>CHAINS</topic><topic>CHIRALITY</topic><topic>ENANTIOMORPHS</topic><topic>PHYSICS OF ELEMENTARY PARTICLES AND FIELDS</topic><topic>RESOLUTION</topic><topic>SCANNING TUNNELING MICROSCOPY</topic><topic>TRANSIENTS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Weckesser, J</creatorcontrib><creatorcontrib>De Vita, A</creatorcontrib><creatorcontrib>Barth, J V</creatorcontrib><creatorcontrib>Cai, C</creatorcontrib><creatorcontrib>Kern, K</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Physical review letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Weckesser, J</au><au>De Vita, A</au><au>Barth, J V</au><au>Cai, C</au><au>Kern, K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mesoscopic correlation of supramolecular chirality in one-dimensional hydrogen-bonded assemblies</atitle><jtitle>Physical review letters</jtitle><addtitle>Phys Rev Lett</addtitle><date>2001-08-27</date><risdate>2001</risdate><volume>87</volume><issue>9</issue><spage>096101</spage><epage>096101</epage><pages>096101-096101</pages><artnum>096101</artnum><issn>0031-9007</issn><eissn>1079-7114</eissn><abstract>The ordering of 4-[trans-2-(pyrid-4-yl-vinyl)] benzoic acid, a two-dimensional chiral species, was studied by scanning tunneling microscopy at noble metal surfaces. Homochiral molecules self-assemble in supramolecular chiral hydrogen-bonded twin chains, which order in nanogratings where the supramolecular chirality is strictly correlated over the entire microm domains without intimate molecular contact. Model simulations indicate that the underlying mesoscopic chiral resolution is associated with twin chains acting as chiroselective templates for transient molecular attachment, which process mediates the gratings' evolution.</abstract><cop>United States</cop><pub>The American Physical Society</pub><pmid>11531578</pmid><doi>10.1103/PhysRevLett.87.096101</doi><tpages>1</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0031-9007 |
ispartof | Physical review letters, 2001-08, Vol.87 (9), p.096101-096101, Article 096101 |
issn | 0031-9007 1079-7114 |
language | eng |
recordid | cdi_osti_scitechconnect_40277473 |
source | American Physical Society:Jisc Collections:APS Read and Publish 2023-2025 (reading list) |
subjects | BENZOIC ACID CHAINS CHIRALITY ENANTIOMORPHS PHYSICS OF ELEMENTARY PARTICLES AND FIELDS RESOLUTION SCANNING TUNNELING MICROSCOPY TRANSIENTS |
title | Mesoscopic correlation of supramolecular chirality in one-dimensional hydrogen-bonded assemblies |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T21%3A15%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Mesoscopic%20correlation%20of%20supramolecular%20chirality%20in%20one-dimensional%20hydrogen-bonded%20assemblies&rft.jtitle=Physical%20review%20letters&rft.au=Weckesser,%20J&rft.date=2001-08-27&rft.volume=87&rft.issue=9&rft.spage=096101&rft.epage=096101&rft.pages=096101-096101&rft.artnum=096101&rft.issn=0031-9007&rft.eissn=1079-7114&rft_id=info:doi/10.1103/PhysRevLett.87.096101&rft_dat=%3Cproquest_osti_%3E71143222%3C/proquest_osti_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c385t-eaaa4a5eb635e5d6e4622c959f9712aa0a3b52781b909c6930a9276828b5562d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=71143222&rft_id=info:pmid/11531578&rfr_iscdi=true |