A Technique for the Rapid Determination of Ionization and Appearance Potentials

A method of obtaining approximate ionization and appearance potentials using a Bendix time-of-flight mass spectrometer was developed. Using this method, which is called the energy compensation technique, ionization and appearance potentials may be obtained usually in less than one minute. The method...

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Published in:Journal of physical chemistry (1952) 1962-01, Vol.66 (5)
Main Authors: Kiser, Robert W., Gallegos, Emilio J.
Format: Article
Language:English
Subjects:
CHEMISTRY
DIAGRAMS
ELECTRIC POTENTIAL
INSTRUMENTS
IONIZATION
MASS SPECTROMETERS
QUANTITATIVE ANALYSIS
SPECTRA
TABLES
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container_title Journal of physical chemistry (1952)
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creator Kiser, Robert W.
Gallegos, Emilio J.
description A method of obtaining approximate ionization and appearance potentials using a Bendix time-of-flight mass spectrometer was developed. Using this method, which is called the energy compensation technique, ionization and appearance potentials may be obtained usually in less than one minute. The method, being instrumental in character, eliminates the necessity of obtaining the usual ionization efficiency curve. Finally, some results of ionization potentials determined for various compounds using the linear extrapolation method, logarithmic plot method, extrapolated voltages difference method, and the energy compensation method are tabulated.
doi_str_mv 10.1021/j100811a507
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ispartof Journal of physical chemistry (1952), 1962-01, Vol.66 (5)
issn 0022-3654
1541-5740
language eng
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source American Chemical Society
subjects CHEMISTRY
DIAGRAMS
ELECTRIC POTENTIAL
INSTRUMENTS
IONIZATION
MASS SPECTROMETERS
QUANTITATIVE ANALYSIS
SPECTRA
TABLES
title A Technique for the Rapid Determination of Ionization and Appearance Potentials
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