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Spectroscopy of high vibrational levels of the N-N stretching mode of N-N- sup 16 O and N-N- sup 18 O
The fundamental and overtones up to {nu} = 6 of the {nu}{sub 3} mode of N{sub 2}{sup 16}O and N{sub 2}{sup 18}O have been studied. The positions of the {nu}{sub 3} overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-...
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| Published in: | Journal of physical chemistry (1952) 1989-03, Vol.93:6 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| container_title | Journal of physical chemistry (1952) |
| container_volume | 93:6 |
| creator | Yamasaki, N.L.S. Manzanares I., C. Baylor, L.C. Schatz, G.C. Weitz, E. |
| description | The fundamental and overtones up to {nu} = 6 of the {nu}{sub 3} mode of N{sub 2}{sup 16}O and N{sub 2}{sup 18}O have been studied. The positions of the {nu}{sub 3} overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-consistent field and configuration interaction calculations and isotopic shift data show that the N-N stretching overtone is best described as a normal mode. Both N{sub 2}{sup 16}O and N{sub 2}{sup 18}O display line widths for the R branch of the {nu} = 6 overtone of less than 2 cm{sup {minus}1}. |
| doi_str_mv | 10.1021/j100343a007 |
| format | article |
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The positions of the {nu}{sub 3} overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-consistent field and configuration interaction calculations and isotopic shift data show that the N-N stretching overtone is best described as a normal mode. Both N{sub 2}{sup 16}O and N{sub 2}{sup 18}O display line widths for the R branch of the {nu} = 6 overtone of less than 2 cm{sup {minus}1}.</description><identifier>ISSN: 0022-3654</identifier><identifier>EISSN: 1541-5740</identifier><identifier>DOI: 10.1021/j100343a007</identifier><language>eng</language><publisher>United States</publisher><subject>400201 - Chemical & Physicochemical Properties ; ABSORPTION SPECTROSCOPY ; CHALCOGENIDES ; CONFIGURATION INTERACTION ; ENERGY LEVELS ; EVEN-EVEN NUCLEI ; EXCITED STATES ; FLUIDS ; FOURIER TRANSFORM SPECTROMETERS ; GASES ; INFRARED SPECTRA ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; ISOTOPES ; LIGHT NUCLEI ; MEASURING INSTRUMENTS ; NITROGEN COMPOUNDS ; NITROGEN OXIDES ; NITROUS OXIDE ; NORMAL-MODE ANALYSIS ; NUCLEI ; OXIDES ; OXYGEN 16 ; OXYGEN 18 ; OXYGEN COMPOUNDS ; OXYGEN ISOTOPES ; ROTATIONAL STATES ; SELF-CONSISTENT FIELD ; SPECTRA ; SPECTROMETERS ; SPECTROSCOPY ; STABLE ISOTOPES ; VIBRATIONAL STATES</subject><ispartof>Journal of physical chemistry (1952), 1989-03, Vol.93:6</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/5040533$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Yamasaki, N.L.S.</creatorcontrib><creatorcontrib>Manzanares I., C.</creatorcontrib><creatorcontrib>Baylor, L.C.</creatorcontrib><creatorcontrib>Schatz, G.C.</creatorcontrib><creatorcontrib>Weitz, E.</creatorcontrib><title>Spectroscopy of high vibrational levels of the N-N stretching mode of N-N- sup 16 O and N-N- sup 18 O</title><title>Journal of physical chemistry (1952)</title><description>The fundamental and overtones up to {nu} = 6 of the {nu}{sub 3} mode of N{sub 2}{sup 16}O and N{sub 2}{sup 18}O have been studied. The positions of the {nu}{sub 3} overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-consistent field and configuration interaction calculations and isotopic shift data show that the N-N stretching overtone is best described as a normal mode. Both N{sub 2}{sup 16}O and N{sub 2}{sup 18}O display line widths for the R branch of the {nu} = 6 overtone of less than 2 cm{sup {minus}1}.</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>ABSORPTION SPECTROSCOPY</subject><subject>CHALCOGENIDES</subject><subject>CONFIGURATION INTERACTION</subject><subject>ENERGY LEVELS</subject><subject>EVEN-EVEN NUCLEI</subject><subject>EXCITED STATES</subject><subject>FLUIDS</subject><subject>FOURIER TRANSFORM SPECTROMETERS</subject><subject>GASES</subject><subject>INFRARED SPECTRA</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>ISOTOPES</subject><subject>LIGHT NUCLEI</subject><subject>MEASURING INSTRUMENTS</subject><subject>NITROGEN COMPOUNDS</subject><subject>NITROGEN OXIDES</subject><subject>NITROUS OXIDE</subject><subject>NORMAL-MODE ANALYSIS</subject><subject>NUCLEI</subject><subject>OXIDES</subject><subject>OXYGEN 16</subject><subject>OXYGEN 18</subject><subject>OXYGEN COMPOUNDS</subject><subject>OXYGEN ISOTOPES</subject><subject>ROTATIONAL STATES</subject><subject>SELF-CONSISTENT FIELD</subject><subject>SPECTRA</subject><subject>SPECTROMETERS</subject><subject>SPECTROSCOPY</subject><subject>STABLE ISOTOPES</subject><subject>VIBRATIONAL STATES</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNqNjkFPAjEQRhsjiSt48g9MuFdnti14NxhPcMA7KWWgJWu72akk_Hsg8eDR05e89w6fUs-EL4QtvR4J0VjjEed3qiFnSbu5xXvVILatNjNnH9SjyBERyRhqFK97DnUoEkp_hrKHmA4RTmk7-JpK9h10fOJObqpGhqVegtSBa4gpH-C77PimrliD_PRAM1iBz7s_5A1WEzXa-0746XfHavqx-Hr_1EVq2khIlUMMJefrl41Di84Y86_oAlypSEs</recordid><startdate>19890323</startdate><enddate>19890323</enddate><creator>Yamasaki, N.L.S.</creator><creator>Manzanares I., C.</creator><creator>Baylor, L.C.</creator><creator>Schatz, G.C.</creator><creator>Weitz, E.</creator><scope>OTOTI</scope></search><sort><creationdate>19890323</creationdate><title>Spectroscopy of high vibrational levels of the N-N stretching mode of N-N- sup 16 O and N-N- sup 18 O</title><author>Yamasaki, N.L.S. ; Manzanares I., C. ; Baylor, L.C. ; Schatz, G.C. ; Weitz, E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_50405333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>ABSORPTION SPECTROSCOPY</topic><topic>CHALCOGENIDES</topic><topic>CONFIGURATION INTERACTION</topic><topic>ENERGY LEVELS</topic><topic>EVEN-EVEN NUCLEI</topic><topic>EXCITED STATES</topic><topic>FLUIDS</topic><topic>FOURIER TRANSFORM SPECTROMETERS</topic><topic>GASES</topic><topic>INFRARED SPECTRA</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>ISOTOPES</topic><topic>LIGHT NUCLEI</topic><topic>MEASURING INSTRUMENTS</topic><topic>NITROGEN COMPOUNDS</topic><topic>NITROGEN OXIDES</topic><topic>NITROUS OXIDE</topic><topic>NORMAL-MODE ANALYSIS</topic><topic>NUCLEI</topic><topic>OXIDES</topic><topic>OXYGEN 16</topic><topic>OXYGEN 18</topic><topic>OXYGEN COMPOUNDS</topic><topic>OXYGEN ISOTOPES</topic><topic>ROTATIONAL STATES</topic><topic>SELF-CONSISTENT FIELD</topic><topic>SPECTRA</topic><topic>SPECTROMETERS</topic><topic>SPECTROSCOPY</topic><topic>STABLE ISOTOPES</topic><topic>VIBRATIONAL STATES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yamasaki, N.L.S.</creatorcontrib><creatorcontrib>Manzanares I., C.</creatorcontrib><creatorcontrib>Baylor, L.C.</creatorcontrib><creatorcontrib>Schatz, G.C.</creatorcontrib><creatorcontrib>Weitz, E.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of physical chemistry (1952)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yamasaki, N.L.S.</au><au>Manzanares I., C.</au><au>Baylor, L.C.</au><au>Schatz, G.C.</au><au>Weitz, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spectroscopy of high vibrational levels of the N-N stretching mode of N-N- sup 16 O and N-N- sup 18 O</atitle><jtitle>Journal of physical chemistry (1952)</jtitle><date>1989-03-23</date><risdate>1989</risdate><volume>93:6</volume><issn>0022-3654</issn><eissn>1541-5740</eissn><abstract>The fundamental and overtones up to {nu} = 6 of the {nu}{sub 3} mode of N{sub 2}{sup 16}O and N{sub 2}{sup 18}O have been studied. The positions of the {nu}{sub 3} overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-consistent field and configuration interaction calculations and isotopic shift data show that the N-N stretching overtone is best described as a normal mode. Both N{sub 2}{sup 16}O and N{sub 2}{sup 18}O display line widths for the R branch of the {nu} = 6 overtone of less than 2 cm{sup {minus}1}.</abstract><cop>United States</cop><doi>10.1021/j100343a007</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-3654 |
| ispartof | Journal of physical chemistry (1952), 1989-03, Vol.93:6 |
| issn | 0022-3654 1541-5740 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5040533 |
| source | ACS CRKN Legacy Archives |
| subjects | 400201 - Chemical & Physicochemical Properties ABSORPTION SPECTROSCOPY CHALCOGENIDES CONFIGURATION INTERACTION ENERGY LEVELS EVEN-EVEN NUCLEI EXCITED STATES FLUIDS FOURIER TRANSFORM SPECTROMETERS GASES INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPES LIGHT NUCLEI MEASURING INSTRUMENTS NITROGEN COMPOUNDS NITROGEN OXIDES NITROUS OXIDE NORMAL-MODE ANALYSIS NUCLEI OXIDES OXYGEN 16 OXYGEN 18 OXYGEN COMPOUNDS OXYGEN ISOTOPES ROTATIONAL STATES SELF-CONSISTENT FIELD SPECTRA SPECTROMETERS SPECTROSCOPY STABLE ISOTOPES VIBRATIONAL STATES |
| title | Spectroscopy of high vibrational levels of the N-N stretching mode of N-N- sup 16 O and N-N- sup 18 O |
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