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Electrocrystallizing C[sub 60]. Synthesis, single crystal X-ray structure, and magnetic (ESR, SQUID) characterization of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][1][sub x]
We report here on the synthesis by electrocrystallization of high quality single crystals of volume up to 1 mm[sup 3] of a salt of formula [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][I][sub x] (0 < x [much lt] 1), the description of its crystal and molecular structure, and its characterization...
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| Published in: | Journal of the American Chemical Society 1993-11, Vol.115:22 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| container_title | Journal of the American Chemical Society |
| container_volume | 115:22 |
| creator | Penicaud, A. Perez-Benitez, A. Gleason, V. Munoz P.E. Escudero, R. |
| description | We report here on the synthesis by electrocrystallization of high quality single crystals of volume up to 1 mm[sup 3] of a salt of formula [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][I][sub x] (0 < x [much lt] 1), the description of its crystal and molecular structure, and its characterization by NIR, EPR, and SQUID magnetic measurements. We have shown that the electrocrystallization technique can be successfully employed to grow large, high-quality single crystals of C[sub 60] salts suitable for X-rays as well as physical studies. The crystal structure of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][I][sub x] shows fully isolated C[sub 60][sup [minus]] anions in a very symmetrical environment. 17 refs., 3 figs. |
| doi_str_mv | 10.1021/ja00075a078 |
| format | article |
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Synthesis, single crystal X-ray structure, and magnetic (ESR, SQUID) characterization of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][1][sub x]</title><source>ACS CRKN Legacy Archives</source><creator>Penicaud, A. ; Perez-Benitez, A. ; Gleason, V. ; Munoz P.E. ; Escudero, R.</creator><creatorcontrib>Penicaud, A. ; Perez-Benitez, A. ; Gleason, V. ; Munoz P.E. ; Escudero, R.</creatorcontrib><description>We report here on the synthesis by electrocrystallization of high quality single crystals of volume up to 1 mm[sup 3] of a salt of formula [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][I][sub x] (0 < x [much lt] 1), the description of its crystal and molecular structure, and its characterization by NIR, EPR, and SQUID magnetic measurements. We have shown that the electrocrystallization technique can be successfully employed to grow large, high-quality single crystals of C[sub 60] salts suitable for X-rays as well as physical studies. The crystal structure of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][I][sub x] shows fully isolated C[sub 60][sup [minus]] anions in a very symmetrical environment. 17 refs., 3 figs.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja00075a078</identifier><language>eng</language><publisher>United States</publisher><subject>400102 - Chemical & Spectral Procedures ; 400201 - Chemical & Physicochemical Properties ; CARBON ; COHERENT SCATTERING ; CRYSTALLIZATION ; DIFFRACTION ; ELECTRON SPIN RESONANCE ; ELEMENTS ; FULLERENES ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MAGNETIC PROPERTIES ; MAGNETIC RESONANCE ; MOLECULAR STRUCTURE ; NONMETALS ; PHASE TRANSFORMATIONS ; PHYSICAL PROPERTIES ; RESONANCE ; SCATTERING ; SYNTHESIS ; X-RAY DIFFRACTION</subject><ispartof>Journal of the American Chemical Society, 1993-11, Vol.115:22</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/5066581$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Penicaud, A.</creatorcontrib><creatorcontrib>Perez-Benitez, A.</creatorcontrib><creatorcontrib>Gleason, V.</creatorcontrib><creatorcontrib>Munoz P.E.</creatorcontrib><creatorcontrib>Escudero, R.</creatorcontrib><title>Electrocrystallizing C[sub 60]. Synthesis, single crystal X-ray structure, and magnetic (ESR, SQUID) characterization of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][1][sub x]</title><title>Journal of the American Chemical Society</title><description>We report here on the synthesis by electrocrystallization of high quality single crystals of volume up to 1 mm[sup 3] of a salt of formula [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][I][sub x] (0 < x [much lt] 1), the description of its crystal and molecular structure, and its characterization by NIR, EPR, and SQUID magnetic measurements. We have shown that the electrocrystallization technique can be successfully employed to grow large, high-quality single crystals of C[sub 60] salts suitable for X-rays as well as physical studies. 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Synthesis, single crystal X-ray structure, and magnetic (ESR, SQUID) characterization of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][1][sub x]</title><author>Penicaud, A. ; Perez-Benitez, A. ; Gleason, V. ; Munoz P.E. ; Escudero, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_50665813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>400102 - Chemical & Spectral Procedures</topic><topic>400201 - Chemical & Physicochemical Properties</topic><topic>CARBON</topic><topic>COHERENT SCATTERING</topic><topic>CRYSTALLIZATION</topic><topic>DIFFRACTION</topic><topic>ELECTRON SPIN RESONANCE</topic><topic>ELEMENTS</topic><topic>FULLERENES</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MAGNETIC PROPERTIES</topic><topic>MAGNETIC RESONANCE</topic><topic>MOLECULAR STRUCTURE</topic><topic>NONMETALS</topic><topic>PHASE TRANSFORMATIONS</topic><topic>PHYSICAL PROPERTIES</topic><topic>RESONANCE</topic><topic>SCATTERING</topic><topic>SYNTHESIS</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Penicaud, A.</creatorcontrib><creatorcontrib>Perez-Benitez, A.</creatorcontrib><creatorcontrib>Gleason, V.</creatorcontrib><creatorcontrib>Munoz P.E.</creatorcontrib><creatorcontrib>Escudero, R.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Penicaud, A.</au><au>Perez-Benitez, A.</au><au>Gleason, V.</au><au>Munoz P.E.</au><au>Escudero, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrocrystallizing C[sub 60]. Synthesis, single crystal X-ray structure, and magnetic (ESR, SQUID) characterization of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][1][sub x]</atitle><jtitle>Journal of the American Chemical Society</jtitle><date>1993-11-03</date><risdate>1993</risdate><volume>115:22</volume><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>We report here on the synthesis by electrocrystallization of high quality single crystals of volume up to 1 mm[sup 3] of a salt of formula [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][I][sub x] (0 < x [much lt] 1), the description of its crystal and molecular structure, and its characterization by NIR, EPR, and SQUID magnetic measurements. We have shown that the electrocrystallization technique can be successfully employed to grow large, high-quality single crystals of C[sub 60] salts suitable for X-rays as well as physical studies. The crystal structure of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][I][sub x] shows fully isolated C[sub 60][sup [minus]] anions in a very symmetrical environment. 17 refs., 3 figs.</abstract><cop>United States</cop><doi>10.1021/ja00075a078</doi></addata></record> |
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| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 1993-11, Vol.115:22 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5066581 |
| source | ACS CRKN Legacy Archives |
| subjects | 400102 - Chemical & Spectral Procedures 400201 - Chemical & Physicochemical Properties CARBON COHERENT SCATTERING CRYSTALLIZATION DIFFRACTION ELECTRON SPIN RESONANCE ELEMENTS FULLERENES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MAGNETIC PROPERTIES MAGNETIC RESONANCE MOLECULAR STRUCTURE NONMETALS PHASE TRANSFORMATIONS PHYSICAL PROPERTIES RESONANCE SCATTERING SYNTHESIS X-RAY DIFFRACTION |
| title | Electrocrystallizing C[sub 60]. Synthesis, single crystal X-ray structure, and magnetic (ESR, SQUID) characterization of [(C[sub 6]H[sub 5])[sub 4]P][sub 2][C[sub 60]][1][sub x] |
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