Surprising differences in the reactivity of cyanoaromatic radical anions generated by photoinduced electron transfer

In this paper, the authors report some studies that indicate that the reactivity of photogenerated cyanoaromatic anion radicals is strongly affected by the medium in which they are generated; interestingly they report conditions under which potentially reactive anion radicals of strongly affected by...

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Bibliographic Details
Published in:Journal of the American Chemical Society 1991-01, Vol.113:1
Main Authors: Kellett, M.A., Whitten, D.G., Gould, I.R., Bergmark, W.R.
Format: Article
Language:English
Subjects:
400500 - Photochemistry
ANTHRACENE
AROMATICS
CHEMICAL REACTIONS
CONDENSED AROMATICS
DATA
ELECTRON TRANSFER
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MEASURING METHODS
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
REDOX REACTIONS
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Summary:In this paper, the authors report some studies that indicate that the reactivity of photogenerated cyanoaromatic anion radicals is strongly affected by the medium in which they are generated; interestingly they report conditions under which potentially reactive anion radicals of strongly affected by the medium in which they are generated; interestingly they report conditions under which potentially reactive anion radicals of DCA and 2,6,9,10-tetracyanoanthracene (TCA) can be the stable end products of photoinduced redox reactions.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00001a052